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Write the mechanism of acid catalysed dehydration of ethanol to give ethene. - Chemistry

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प्रश्न

Write the mechanism of acid catalysed dehydration of ethanol to give ethene.

संक्षेप में उत्तर

उत्तर

Mechanism of acid catlaysed dehydration of ethanol:

Step 1: Protonation of ethanol

\[\begin{array}{cc}
\phantom{...............................}\ce{H}\\
\phantom{...............................}|\\
\ce{\underset{(Ethanol)}{CH3 - CH2 - \underset{\bullet\bullet}{\overset{\bullet\bullet}{O}}} - H ->[H - OSO3H] CH3 - CH2 - \underset{⊕}{O} - H + HS\overset{Θ}{O4}}
\end{array}\]

Step 2: Elimination of water molecule

\[\begin{array}{cc}
\ce{H}\phantom{....................}\\
|\phantom{....................}\\
\ce{CH2 - CH2 - O - H -> \underset{(Ethene)}{CH2 = CH2} + H2O + H^+}\\
|\phantom{................................................}\\
\ce{H}\phantom{................................................}
\end{array}\]

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अध्याय 11: Hydroxy Compounds and Ethers - Evaluation [पृष्ठ १४२]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 12 TN Board
अध्याय 11 Hydroxy Compounds and Ethers
Evaluation | Q 10. | पृष्ठ १४२
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