HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)
Academic Year: 2022-2023
Date & Time: 1st March 2023, 11:00 am
Duration: 3h
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General instructions :
The question paper is divided into four sections :
- Section A: Q. No. 1 contains Ten multiple-choice type of questions carrying One mark each. Q. No. 2 contains Eight very short answer type of questions carrying One mark each.
- Section B: Q. No. 3 to Q. No. 14 contain Twelve short answer type of questions carrying Two marks each. (Attempt any Eight).
- Section C: Q. No. 15 to Q. No. 26 contains Twelve short answer type of questions carrying Three marks each. (Attempt any Eight).
- Section D: Q. No. 27 to Q. No. 31 contain Five long answer type of questions carrying Four marks each. (Attempt any Three).
- Use of the log table is allowed. Use of calculator is not allowed.
- Figures to the right indicate full marks.
- For each multiple-choice type of question, it is mandatory to write the correct answer along with its alphabet. e.g., (a)......../(b)......../(c)......./(d)........
No marks(s) shall be given if ONLY the correct answer or the alphabet of the correct answer is written. Only the first attempt will be considered for evaluation.
Given:
R = 8.314 J.K–1. mol–1
NA = 6.022 × 1023
F = 96500C
The relation between the radius of the sphere and the edge length in the body-centred cubic lattice is given by the formula ______.
`sqrt(3)r` = 4a
r = `sqrt(3)/a xx 4`
r = `sqrt(3)/4a`
r = `sqrt(2)/4 xx a`
Chapter: [0.01] Solid State
The pH of a weak monoacidic base is 11.2, and its OH– ion concentration is ______.
1.585 × 10–3 mol dm–3
3.010 × 10–11 mol dm–3
3.010 × 10–3 mol dm–3
1.585 × 10–11 mol dm–3
Chapter: [0.03] Ionic Equilibria
Which of the following correctly represents integrated rate law equation for a first order reaction in a gas phase?
k = `2.303/t xx log_10 P_i/(P_i - P)`
k = `2.303/t xx log_10 P_i/(2P_i - P)`
k = `2.303/t xx log_10 (2P_i)/(P_i - P)`
k = `2.303/t xx log_10 (P_i - P)/(2P_i)`
Chapter: [0.06] Chemical Kinetics
The spin only magnetic moment of Mn2+ ion is ______.
4.901 BM
5.916 BM
3.873 BM
2.846 BM
Chapter: [0.08] Transition and Inner Transition Elements
The correct formula of a complex having IUPAC name Tetraamminedibromoplatinum (IV) bromide is ______.
[Pt Br (NH3)4] Br2
[Pt Br2 (NH3)4] Br
[Pt Br2 (NH3)4] Br2
[Pt Br (NH3)4] Br
Chapter: [0.09] Coordination Compounds
The allylic halide, among the following, is ______.
\[\begin{array}{cc}
\phantom{}\ce{R - CH - R}\phantom{}\\
|\phantom{..}\\
\ce{X}\phantom{..}
\end{array}\]
CH2 = CH – X
CH2 = CH – CH2 – X
Chapter: [0.1] Halogen Derivatives
The product of following reaction is
\[\ce{CH3 - CH = CH - CH2 - CHO ->[i) LiAlH4][ii) H3O+]}\] ______?
CH3 – CH2 – CH2 – CH2 – CH2 – OH
CH3 – CH = CH – CH2 – CH2 – OH
CH3 – CH2 – CH2 – CH2 – COOH
CH3 – CH = CH – CH2 – COOH
Chapter: [12.01] Aldehydes and Ketones
Ozonolysis of 2, 3 dimethyl but-2-ene, followed by decomposition by Zn dust and water gives ______.
acetaldehyde
propionaldehyde and acetone
acetone
acetaldehyde and butyraldehyde
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
The glycosidic linkage present in maltose is ______.
α, β-1, 2-glycosidic linkage
α-1, 4-glycosidic linkage
β-1, 4-glycosidic linkage
α-1, 6-glycosidic linkage
Chapter: [0.14] Biomolecules
The monomer of natural rubber is ______.
Isoprene
Acrylonitrile
ε-Caprolactam
Tetrafluoroethylene
Chapter: [0.15] Introduction to Polymer Chemistry [0.15] Polymers
Write the name of the technique used to know geometry of nanoparticles.
Chapter: [0.16] Green Chemistry and Nanochemistry
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Chapter: [0.13] Amines [13.01] Amines
Write the structure of the product formed when chlorobenzene is treated with sodium metal in the presence of dry ether.
Chapter: [0.1] Halogen Derivatives
Write the chemical composition of cryolite.
Chapter: [0.07] Elements of Groups 16, 17 and 18
Write the name of platinum complex used in the treatment of cancer.
Chapter: [0.09] Coordination Compounds
Write the SI unit of the cryoscopic constant.
Chapter: [0.02] Solutions
Write the correct condition for spontaneity in terms of Gibbs energy.
Chapter: [0.04] Chemical Thermodynamics
Calculate molar conductivity for 0.5 M BaCl2 if its conductivity at 298K is 0.01 Ω–1 cm–1.
Chapter: [0.05] Electrochemistry
Distinguish between lanthanoid and actinoids.
Chapter: [0.08] Transition and Inner Transition Elements [8.02] F-block Elements
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Calculate the mole fraction of solute, if the vapour pressure of pure benzene at a certain temperature is 640 mmHg and the vapour pressure of a solution of a solute in benzene is 600 mmHg.
Chapter: [0.02] Solutions
Define Green chemistry.
Chapter: [0.16] Green Chemistry and Nanochemistry
Write any three advantages of nanoparticles and nanotechnology.
Chapter: [0.16] Green Chemistry and Nanochemistry
Explain the following term:
Substitutional impurity defect
Chapter: [0.01] Solid State
Explain the following term:
Interstitial impurity defect
Chapter: [0.01] Solid State
Write the chemical reaction for the following:
Chlorobenzene is heated with fuming H2SO4.
Chapter: [0.1] Halogen Derivatives
What is the action of the following on ethyl bromide:
silver acetate
Chapter: [10.01] Haloalkanes
Define Acidic buffer solution.
Chapter: [0.03] Ionic Equilibria
Write the relationship between solubility and solubility product for PbI2.
Chapter: [0.03] Ionic Equilibria
What is the action of the following reagents on ethyl amine?
Chloroform and caustic potash
Chapter: [13.01] Amines
What is the action of the following reagents on ethyl amine?
Nitrous acid
Chapter: [13.01] Amines
Calculate standard Gibbs energy change at 25°C for the cell reaction.
\[\ce{Cd_{(s)} + Sn^{2+}_{ (aq)} -> Cd^{2+}_{ (aq)} + Sn_{(s)}}\]
\[\ce{E^0_{cd}}\] = –0.403 V, \[\ce{E^0_{Sn}}\] = –0.136 V
Chapter: [0.05] Electrochemistry
Explain the preparation of glucose from sucrose.
Chapter: [0.14] Biomolecules
Write the structure of D-ribose.
Chapter: [0.14] Biomolecules
Define the Extensive properties.
Chapter: [0.04] Chemical Thermodynamics
Calculate the work done during the expansion of 2 moles of an ideal gas from 10 dm3 to 20 dm3 at 298 K in a vacuum.
Chapter: [0.04] Chemical Thermodynamics
Write the preparation of nylon 6, 6.
Chapter: [0.15] Introduction to Polymer Chemistry
Draw the structure of chloric acid.
Chapter: [0.07] Elements of Groups 16, 17 and 18
Draw the structure of the following compound:
Peroxy disulphuric acid
Chapter: [0.07] Elements of Groups 16, 17 and 18
Explain the term osmosis.
Chapter: [0.02] Solutions [0.02] Solutions and Colligative Properties
How will you determine the molar mass of non-volatile solute by elevation of boiling point?
Chapter: [0.02] Solutions
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Convert the following:
Ethyl alcohol into ethyl acetate
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
How is phenol converted into the following?
benzene
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
How will you obtain the following? (Give balanced equation.)
Ethyl chloride from diethyl ether.
Chapter: [11.03] Ethers
A weak monobasic acid is 10% dissociated in 0.05 M solution. What is the percent dissociation in 0.15 M solution?
Chapter: [0.03] Ionic Equilibria
Explain the dehydrohalogenation reaction of 2-chlorobutane.
Chapter: [0.1] Halogen Derivatives
Write environmental effect of CFC.
Chapter: [0.1] Halogen Derivatives
2000 mmol of an ideal gas expanded isothermally and reversibly from 20 L to 30 L at 300 K, calculate the work done in the process (R = 8.314 JK–1 mol–1).
Chapter: [0.04] Chemical Thermodynamics
What are interstitial compounds?
Chapter: [0.08] Transition and Inner Transition Elements
Give the classification of alloys with examples.
Chapter: [0.08] Transition and Inner Transition Elements
Draw labelled diagram of H2 – O2 fuel cell.
Chapter: [0.05] Electrochemistry
Write two applications of fuel cells.
Chapter: [0.05] Electrochemistry
Explain the formation of [CoF6]3Θ complex with respect to
- Hybridisation
- Magnetic properties
- Inner/outer complex
- Geometry
Chapter: [0.09] Coordination Compounds
Explain pseudo-first-order reaction with an example.
Chapter: [0.06] Chemical Kinetics
Derive integrated rate law for a zero-order reaction \[\ce{A -> Product}\].
Chapter: [0.06] Chemical Kinetics
Explain Aldol condensation of ethanal.
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
Explain anomalous behaviour of oxygen in group 16 with respect to:
- Atomicity
- Magnetic property
- Oxidation state
Chapter: [0.07] Elements of Groups 16, 17 and 18 [7.02] Group 16 Elements
How will you prepare acetic anhydride from acetic acid?
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
Write chemical reactions for the following conversion:
Acetic acid into ethyl alcohol
Chapter: [0.11] Alcohols, Phenols and Ethers [11.01] Alcohols [11.02] Phenols [11.03] Ethers
Write the IUPAC name of methylphenylamine.
Chapter: [0.13] Amines
Write the structure of methylphenylamine.
Chapter: [0.13] Amines
Show that the time required for 99.9% completion of a first-order reaction is three times the time required for 90% completion.
Chapter: [0.06] Chemical Kinetics
Give the electronic configuration of gadolinium (Z = 64).
Chapter: [0.08] Transition and Inner Transition Elements
Answer the following
Which nanomaterial is used for tyres of the car to increase the life of tyres?
Chapter: [0.16] Green Chemistry and Nanochemistry
Obtain the relationship between ΔH and ΔU for gas phase reactions.
Chapter: [0.04] Chemical Thermodynamics
Answer the following in one sentence.
Define the term: Vulcanization
Chapter: [0.15] Introduction to Polymer Chemistry [0.15] Polymers
Silver crystallizes in the fcc structure. If the edge length of the unit cell is 400 pm, calculate the density of silver (Atomic mass of Ag = 108).
Chapter: [0.01] Solid State
Explain haloform reaction with suitable example.
Chapter: [0.12] Aldehydes, Ketones and Carboxylic Acids
Define Distereoisomers.
Chapter: [0.09] Coordination Compounds
Give cis isomer of [Co(NH3)4Cl2]⊕.
Chapter: [0.09] Coordination Compounds
Give trans isomer of [Co(NH3)4Cl2]⊕.
Chapter: [0.09] Coordination Compounds
Define Reference electrode
Chapter: [0.05] Electrochemistry
Give reason:
Bleaching action of ozone is also called dry bleach.
Chapter: [0.07] Elements of Groups 16, 17 and 18
Write Dow process for the preparation of Phenol.
Chapter: [11.02] Phenols
What is the action of bromine water on carbolic acid?
Chapter: [11.02] Phenols
Elements of group 16 have lower ionization enthalpy values compared to those of group 15 elements. Explain why?
Chapter: [0.07] Elements of Groups 16, 17 and 18
Write two uses of dioxygen.
Chapter: [7.02] Group 16 Elements
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