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Carbon Dioxide

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Topics

  • Carbon Dioxide: Properties and Importance
  • Experiment
  • Physical and Chemical Properties
  • Uses of Carbon Dioxide

Carbon Dioxide: Properties and Importance

Carbon dioxide (CO₂) is a chemical compound consisting of molecules where one carbon atom is covalently double-bonded to two oxygen atoms. The molecular mass of CO₂ is 44 g/mol. It is an essential component of Earth's atmosphere and plays a significant role in various biological and chemical processes. CO₂ has a melting point of -56.6°C, indicating it transitions from solid to gas at very low temperatures under standard atmospheric conditions. At room temperature, it exists as a gas and is odourless at typical concentrations. As the primary carbon source for the carbon cycle, atmospheric CO₂ is essential for sustaining life on Earth. While transparent to visible light, carbon dioxide absorbs infrared radiation, contributing to its role as a greenhouse gas. It is also soluble in water and can be found in groundwater, lakes, ice caps, and seawater.

  • Carbon dioxide is present in the air in a free state, constituting about 0.03% of the atmosphere. It is an essential greenhouse gas that helps regulate Earth's temperature.
  • The air we exhale contains about 4% carbon dioxide, as it is a byproduct of respiration.
  • Carbon dioxide is found in the form of salts, such as calcium carbonate, which is present in chalk, Shahabad tiles, marble, and limestone.
  • CO₂ is released during the combustion of wood, fossil fuels like coal, and other organic materials. This process is a significant source of carbon dioxide in the environment.

Experiment

1. Aim: To prepare carbon dioxide (CO₂) gas by the reaction of calcium carbonate with dilute hydrochloric acid and collect it.

2. Requirements

  • Apparatus: retort stand, round-bottom flask, thistle funnel, gas delivery tube, gas jars.
  • Chemicals: Calcium carbonate (e.g., marble or limestone pieces), dilute hydrochloric acid (HCl).

3. Procedure

  • Assemble the apparatus as shown in the figure. Place calcium carbonate (CaCO₃) in the round-bottom flask.
  • Add dilute hydrochloric acid to the flask through the thistle funnel, ensuring the funnel's end is dipped in the acid.
  • The reaction between CaCO₃ and HCl produces carbon dioxide gas (CO₂).
  • Collect the CO₂ gas in gas jars by upward displacement of air.

 Preparation of Carbon Dioxide

4. Chemical Equation

CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂ ↑

5. Conclusion: Carbon dioxide is successfully prepared by the reaction of calcium carbonate with dilute hydrochloric acid. The gas is collected in gas jars, demonstrating the upward displacement of air due to CO₂ being heavier than air.

Physical and Chemical Properties:

Observe the colour of the gas formed in the above experiment.

Smell the gas in the gas jar.

Use separate gas jars for the activities below:

  • Remove the lid of a gas jar and put some limewater in it.
  • Place a burning candle in a gas jar.
  • Drop a small amount of a solution of some universal indicator in one gas jar filled with CO₂ and shake it.
  • Pour some water in a gas jar and shake it.
  • Moisten a blue and a red litmus paper and drop them in a gas jar of CO₂.

Physical Properties of CO₂:

Test Observations
Odour Odourless
Colour Colourless

Chemical Properties of CO₂:

Test Observations
Burning candle Extinguishes the flame, showing CO₂ does not support combustion.
Universal indicator Turns the indicator solution yellow or orange, indicating acidic nature.
Limewater Turns limewater milky, indicating the presence of CO₂.
Water Dissolves slightly in water to form carbonic acid.
Litmus paper Blue litmus turns red, confirming CO₂ is acidic.

Some More Chemical Properties of Carbon Dioxide:

1. Sodium carbonate is formed when carbon dioxide is passed through an aqueous solution of sodium hydroxide (Sodium carbonate = washing soda)

Chemical equation of the reaction: 2NaOH + CO₂ → Na₂CO₃ + H₂O

2. Sodium bicarbonate is formed on passing CO₂ through an aqueous solution of sodium carbonate (Sodium bicarbonate = baking soda)

Chemical equation of the reaction: Na₂CO₃ + H₂O + CO₂ → 2NaHCO₃

3. Write down the equation of the chemical reaction taking place between water and carbon dioxide in the above experiment.

CO2+H2OH2CO3

4. Write down the equation of the chemical reaction taking place on putting limewater in the gas jar of CO₂.

Ca(OH)2+CO2CaCO3+H2O

Uses of Carbon Dioxide:

  1. CO₂ is used in aerated drinks to add fizz and create carbonation.
  2. Solid CO₂, known as dry ice, is used in cold storage to keep milk, milk products, and frozen items cool during transportation.
  3. Dry ice is also used to create mist effects in dramas and movies.
  4. CO₂ produced through chemical reactions or stored under pressure is used in fire extinguishers to put out fires.
  5. Liquefied CO₂ is used to remove caffeine from coffee in a decaffeination process.
  6. Liquid CO₂ acts as an eco-friendly solvent for modern dry cleaning methods.
  7. CO₂ is essential for plants, as they use it from the air for photosynthesis to produce food.
  8. It is also used in welding processes to shield the welding arc from contamination.
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