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प्रश्न
Answer in brief.
What are ionization isomers ? Give an example.
उत्तर
Isomers that involve the exchange of ligands between coordination and ionization spheres are called ionization isomers.
e.g. [Co(NH3)5SO4]Br and [Co(NH3)5Br]SO4
संबंधित प्रश्न
List various types of isomerism possible for coordination compounds, giving an example of each.
Answer the following in one or two sentences.
Predict whether the [Cr(en)2(H2O)2]3+ complex is chiral. Write the structure of its enantiomer.
Answer the following question.
Draw isomers of the following
Ru(NH3)4Cl2
The pair [Co(NH3)5(SO4)]Br and [Co(NH3)5Br]SO4 exhibits ____________ isomerism
Which type of isomerism is exhibited by [Pt(NH3)2Cl2]?
Which one of the following pairs represents linkage isomers?
Draw all possible geometrical isomers of the complex \[\ce{[Co(en)2Cl2]^+}\] and identify the optically active isomer.
Explain optical isomerism in coordination compounds with an example.
What are hydrate isomers? Explain with an example.
Identify the CORRECT statement about the following complex of platinum.
[PtCl2(en)2]2+
Consider the two complexes given below:
\[\ce{\underset{(I)}{[Co(NH3)5SO4]Br}}\] and \[\ce{\underset{(II)}{[Co(NH3)5Br]SO4}}\]
I and II are ____________ isomers.
The formula of two complexes X and Y of chromium are given below:
\[\ce{\underset{(X)}{[Cr(H2O)6]Cl3}}\] and \[\ce{\underset{(Y)}{[Cr(H2O)5Cl]Cl2.H2O}}\]
X and Y are examples of ____________ isomers.
Geometrical isomerism is not shown by
The correct structure of Fe(CO)5 is
Which of the following does not show optical isomerism?
Complex [COCl2(en)2]+ can
Which of the following compound show optical isomerism?
Which of the following compound is optically active?
Which among the following solid is a non-polar solid?
Give cis isomer of [Co(NH3)4Cl2]⊕.
Explain the ionisation isomers.
Draw the structure of cis isomers of Pt(NH3)2Cl2.
Draw the structure of trans isomers of Pt(NH3)2Cl2.
Give a chemical test to show that \[\ce{[Co(NH3)5Cl]SO4}\] and \[\ce{[Co(NH3)5SO4]CI}\] are ionisation isomers.
Three organic compounds A, B and C are non cyclic functional isomers of carbonyl compounds with molecular formula C4H8O. Isomers A and C give positive Tollen’s test while compound B does not give positive Tollen’s test but gives positive iodoform test. Compounds A and B on reduction with Zn amalgam and conc. HCl give the same product.
- Write the structures of the compounds A, B and C.
- Out of the compounds A, B and C, which one will be the least reactive towards addition of HCN.
