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प्रश्न
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Account for the following:
Primary amines (R-NH2) have higher boiling point than tertiary amines (R3N).
उत्तर
Primary amines exhibit intermolecular hydrogen bonding, necessitating greater energy to disrupt the attraction. In tertiary amines, intermolecular hydrogen bonding is absent.
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संबंधित प्रश्न
Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2
Complete the following acid-base reaction and name the product:
\[\ce{CH3CH2CH2NH2 + HCl ->}\]
Give reasons CH3NH2 is more basic than C6H5NH2.
Illustrate the following reactions giving suitable example in each case
Ammonolysis
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Arrange the following compounds in increasing order of their boiling points.
Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane
Which among the following has the highest boiling point?
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
Write short note on the following:
Ammonolysis
