Advertisements
Advertisements
प्रश्न
The product of the following reaction is
\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{C2H5 - C - CH3 ->[H2/Ni][\Delta] \phantom{..}?}\end{array}\]
पर्याय
\[\ce{CH3 - CH2 - CH2 - CH2 - OH}\]
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]\[\ce{CH3 - CH2 - CH2 - CH3}\]
\[\ce{CH3 - CH2 - CH2 - COOH}\]
उत्तर
\[\begin{array}{cc}
\ce{CH3 - CH - CH2 - CH3}\\
|\phantom{.........}\\
\ce{OH}\phantom{.......}
\end{array}\]
Explanation:
\[\begin{array}{cc}
\ce{O}\phantom{...............................}\\
||\phantom{...............................}\\
\ce{\underset{(2-Butanone)}{C2H5 - C - CH3} ->[H2/Ni][\Delta]\phantom{..} CH3 - CH - CH2 CH3}\\
\phantom{....................}|\\
\phantom{......................}\ce{\underset{(2-Butanol)}{OH}}\\
\end{array}\]
APPEARS IN
संबंधित प्रश्न
Predict the products of the following reactions:
Draw the structure of the semicarbazone of ethanal.
Arrange the following compound in increasing order of its reactivity in nucleophilic addition reactions.
Ethanal, Propanal, Propanone, Butanone.
Hint: Consider steric effect and electronic effect.
Predict the product of the following reaction:
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
What is meant by the following term? Give an example of the reaction in the following case.
Hemiacetal
Complete the synthesis by giving missing starting material, reagent or product.
\[\ce{C6H5CHO ->[H2NCONHNH2]}\]
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
How are the following compounds prepared?
acetophenone from benzene
How are the following compounds prepared?
benzaldehyde from benzoyl chloride
Write balanced chemical equations for action of ammonia on - acetone
Which of the following is the correct representation for intermediate of nucleophilic addition reaction to the given carbonyl compound (A):
(i) 
(ii) 
(iii) 
(iv) 
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
Reaction of aqueous sodium hydroxide on chlorobenzene gives which of the following products?
Which of the following has the most acidic hydrogen?
What happens when ethanal is treated with excess ethanol and acid?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative:
Acetaldehydedimethylacetal
Draw the structure of the following derivative.
Acetaldehydedimethylacetal
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Give an example of the reaction in the following case.
Imine
