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प्रश्न
Which would undergo SN2 reaction faster in the following pair and why ?
CH3 – CH2 – Br and CH3 – CH2 – I
उत्तर
CH3 – CH2 – I would undergo an SN2 reaction faster than CH3 – CH2 – Br. Since iodine is a better leaving group because of its large size, it will be released at a faster rate in the presence of an incoming nucleophile as compared to bromine.
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संबंधित प्रश्न
Write the isomers of the compound having the formula C4H9Br.
Write the structure of the major organic product in the following reaction:
\[\ce{CH3CH2CH2OH + SOCl2 ->}\]
Which of the following is an example of SN2 reaction?
SN2 mechanism proceeds through intervention of ____________.
Which of the following compounds is optically active?
SN1 reaction of alkyl halides lead to ___________.
The reaction of C6H5–CH=CH–CH3 with HBr produces:
Which of the following statements are correct about the kinetics of this reaction?
(i) The rate of reaction depends on the concentration of only (b).
(ii) The rate of reaction depends on concentration of both (a) and (b).
(iii) Molecularity of reaction is one.
(iv) Molecularity of reaction is two.
Which of the compounds will react faster in SN1 reaction with the –OH ion?
\[\ce{CH3-CH2-Cl}\] or \[\ce{C6H5-CH2-Cl}\]
Match the reactions given in Column I with the types of reactions given in Column II.
| Column I | Column II | |
| (i) |  |
(a) Nucleophilic aromatic substitution |
| (ii) | \[\begin{array}{cc} \ce{CH3 - CH = CH2 + HBr -> CH3 - CH - CH3}\\ \phantom{............................}|\phantom{}\\ \phantom{.............................}\ce{Br}\phantom{} \end{array}\] |
(b) Electrophilic aromatic substitution |
| (iii) |  |
(c) Saytzeff elimination |
| (iv) |  |
(d) Electrophilic addition |
| (v) | \[\begin{array}{cc} \ce{CH3 CH2 CH CH3 ->[alc.KOH] CH3 CH = CH CH3}\\ \phantom{}|\phantom{..........................}\\ \phantom{}\ce{Br}\phantom{........................} \end{array}\] |
(e) Nucleophilic substitution (SN1) |
