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प्रश्न
Why is FeO (s) not formed in stoichiometric composition?
उत्तर
In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.
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संबंधित प्रश्न
Give reasons : In stoichiometric defects, NaCl exhibits Schottky defect and not Frenkel defect.
Examine the given defective crystal:
Answer the following questions :
(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances show such defect?
What type of defect is shown by NaCl in
stoichiometric defects, and
The radius of Cs+ is 169 pm and Cl− is 181 pm. The radius ratio is ____________.
Type of stoichiometric defect shown by ZnS is ____________.
Which of the following crystals does not exhibit Frenkel defect?
What is the effect of Frenkel defect on the density of ionic solids?
In a Schottky defect ____________.
Given below are two statements, one is labelled as Assertion (A) and the other is labelled as Reason (R):
Assertion: In any ionic solid (MX) with Schottky defects, the number of positive and negative ions are same.
Reason: Equal number of cation and anion vacancies are present.
The incorrect statement about the imperfections in solids is ______.
