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Why is FeO (s) not formed in stoichiometric composition? - Chemistry

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Why is FeO (s) not formed in stoichiometric composition?

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Solution

In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.

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Chapter 1: Solid States - Exercises [Page 10]

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NCERT Exemplar Chemistry [English] Class 12
Chapter 1 Solid States
Exercises | Q III. 58. | Page 10

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