Advertisements
Advertisements
Question
Why is FeO (s) not formed in stoichiometric composition?
Solution
In the crystals of FeO, some of the Fe2+ cations are replaced by Fe3+ ions. Three Fe2+ ions are replaced by two Fe3+ ions to make up for the loss of positive charge. Eventually there would be less amount of metal as compared to stoichiometric proportion.
APPEARS IN
RELATED QUESTIONS
Explain the following terms with suitable examples: Frenkel defect
Out of NaCl and AgCl, which one shows Frenkel defect and why?
Defect shown by non-ionic solids is ____________.
Defects in solids can be studied using
Frenkel defects are not found in alkali metal halides because ____________.
The radius of Cs+ is 169 pm and Cl− is 181 pm. The radius ratio is ____________.
Assertion: Due to Frenkel defect, there is no effect on the density of the crystalline solid.
Reason: In Frenkel defect, no cation or anion leaves the crystal.
Which of the following crystals does not exhibit Frenkel defect?
Which of the following point defects are shown by AgBr(s) crystals?
- Schottky defect
- Frenkel defect
- Metal excess defect
- Metal deficiency defect
Which type of 'defect' has the presence of cations in the interstitial sites?