Advertisements
Advertisements
प्रश्न
Write balanced chemical equations for action of ammonia on - acetone
उत्तर
APPEARS IN
संबंधित प्रश्न
Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:
C6H5COCH3, CH3-CHO, CH3COCH3
Predict the products of the following reactions:
Write the products formed when CH3CHO reacts with the following reagents : H2N – OH
Predict the product of the following reaction:
What is meant by the following term? Give an example of the reaction in the following case.
Acetal
How will you bring about the following conversion in not more than two steps?
Bromobenzene to 1-Phenylethanol
Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
How will you convert sodium acetate to methane?
Write the main product formed when propanal reacts with the following reagents:
2 moles of 3 CH OH in presence of dry HCl
How will you convert benzoic acid to m-bromobenzoic acid?
Which of the following compounds is most reactive towards nucleophilic addition reactions?
Benzaldehyde can be obtained from benzal chloride. Write reactions for obtaining benzalchloride and then benzaldehyde from it.
Alkenes 
and carbonyl compounds 
, both contain a π bond but alkenes show electrophilic addition reactions whereas carbonyl compounds show nucleophilic addition reactions. Explain.
Identify the compounds A, B and C in the following reaction.
\[\ce{CH3 - Br ->[Mg/ether] (A) ->[(i) CO][(ii) Water] (B) ->[CH3OH/H+][Δ] (C)}\]
The pH of blood does not appreciably change by a small addition of acid or base because
Which one of the following gives only one monochloro derivative?
Which of the following has the most acidic hydrogen?
The most stable reagent for the conversion of R – CH2OH → RCHO is
Which among the following is most reactive to give nucleophilic addition?
Write the name of product formed, when acetone is treated with 2, 4-dinitrophenyl hydrazine.
Which of the following is most reactive in nucleophilic addition reactions?
The following questions are case-based questions. Read the passage carefully and answer the questions that follow:
| The carbon-oxygen double bond is polarised in aldehydes and ketones due to higher electronegativity of oxygen relative to carbon. Therefore, they undergo nucleophilic addition reactions with a number of nucleophiles such as HCN, NaHSO3, alcohols, ammonia derivatives and Grignard reagents. Aldehydes are easily oxidised by mild oxidising agents as compared to ketones. The carbonyl group of carboxylic acid does not give reactions of aldehydes and ketones. Carboxylic acids are considerably more acidic than alcohols and most of simple phenols. |
Answer the following:
(a) Write the name of the product when an aldehyde reacts with excess alcohol in the presence of dry HCl. (1)
(b) Why carboxylic acid is a stronger acid than phenol? (1)
(c) (i) Arrange the following compounds in increasing order of their reactivity towards CH3MgBr: (1)
CH3CHO, \[\begin{array}{cc}
\ce{(CH3)3C-C-CH3}\\
\phantom{....}||\\
\phantom{....}\ce{O}
\end{array}\], \[\begin{array}{cc}
\ce{CH3-C-CH3}\\
||\\
\ce{O}
\end{array}\]
(ii) Write a chemical test to distinguish between propanal and propanone. (1)
OR
(c) Write the main product in the following: (2)
| (i) |  |
| (ii) |  |
Draw structures of the given derivatives.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
The ethylene ketal of hexane-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw the structure of the following derivative.
The ethylene ketal of hexan-3-one
Draw structure of the following derivative.
The ethylene ketal of hexan-3-one
