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Write the Order of Thermal Stability of the Hydrides of Group 16 Elements. - Chemistry

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प्रश्न

Write the order of thermal stability of the hydrides of Group 16 elements.

उत्तर १

The thermal stability of hydrides decreases on moving down the group. This is due to a decrease in the bond dissociation enthalpy (H−E) of hydrides on moving down the group.

Therefore,

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उत्तर २

The thermal stability of hydrides of group 16 elements decreases down the group. This is because down the group, size of the element (M) increases, M-H bond length increases and thus, stability of M-H bond decreases so that it can be broken down easily. Hence, we have order of thermal stability as H2O > H2S > H2Se > H2Te > H2PQ

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पाठ 7: The p-block Elements - Intext Questions [पृष्ठ १८३]

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एनसीईआरटी Chemistry [English] Class 12
पाठ 7 The p-block Elements
Intext Questions | Q 14 | पृष्ठ १८३

संबंधित प्रश्‍न

a. Explain the trends in the following properties with reference to group 16:

1 Atomic radii and ionic radii

2 Density

3 ionisation enthalpy

4 Electronegativity

b. In the electolysis of AgNO3 solution 0.7g of Ag is deposited after a certain period of time. Calulate the quantity of electricity required in coulomb. (Molar mass of Ag is 107.9g mol-1)

 


Account for the following : There is large difference between the melting and boiling points of oxygen and sulphur.


Why is H2O a liquid and H2S a gas?


Why does NH3 form hydrogen bond but PH3 does not?


Knowing the electron gain enthalpy values for O → O and O → O2− as −141 and 702 kJ mol−1 respectively, how can you account for the formation of a large number of oxides having O2− species and not O? (Hint: Consider lattice energy factor in the formation of compounds).


Explain why inspite of nearly the same electronegativity, oxygen forms hydrogen bonding while chlorine does not.


Arrange the following in the order of property indicated for each set:

 F2, Cl2, Br2, I2 - increasing bond dissociation enthalpy.


Give reasons Thermal stability decreases from H2O to H2Te.


Draw the structures of `H_3PO_2`

 


Arrange the following in order of the property indicated set.
HF, HCl, HBr, HI - decreasing bond enthalpy.


The boiling points of hydrides of group 16 are in the order:


The formation of \[\ce{O^+_2[PtF6]^-}\] is the basis for the formation of first xenon compound. This is because ____________.


Match the items of Columns I and II and mark the correct option.

Column I Column II
(A) \[\ce{H2SO4}\] (1) Highest electron gain enthalpy
(B) \[\ce{CCl3NO2}\] (2) Chalcogen
(C) \[\ce{Cl2}\] (3) Tear gas
(D) Sulphur (4) Storage batteries

Strong reducing behaviour of \[\ce{H3PO2}\] is due to ______.


Write a balanced chemical equation for the reaction showing catalytic oxidation of NH3 by atmospheric oxygen.


______ is a radioactive element in group 16 elements.


______ is a gaseous element of group 16.


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