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Define terms: Fuel cell
Concept: Batteries > Primary Batteries
Write the chemical equation involved in the following reaction:
Hoffmann-bromamide degradation reaction
Concept: Amines > Preparation of Amines
Write the chemical equation involved in the following reaction:
Hoffmann-bromamide degradation reaction
Concept: Amines > Preparation of Amines
Draw the structures of the HClO3.
Concept: P - Block Group 17 Elements > Oxoacids of Halogens
On the basis of crystal field theory, write the electronic configuration for d4 ion if ∆0 < P.
Concept: Bonding in Coordination Compounds > Crystal Field Theory (CFT)
What is Lanthanoid contraction?
Concept: F-block Elements > The Lanthanoids
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume :
SO2Cl2 (g) → SO2 (g) + Cl2 (g)
Experiment | Time/s–1 | Total pressure/atm |
1 | 0 | 0.4 |
2 | 100 | 0.7 |
Calculate the rate constant.
(Given : log 4 = 0.6021, log 2 = 0.3010)
Concept: Factors Influencing Rate of a Reaction
Account for the following : Nitrogen does not form pentahalide.
Concept: p-Block elements of Group 15 Elements > Dinitrogen
State Henry’s law.
Concept: Solubility > Solubility of a Gas in a Liquid
Define limiting molar conductivity.
Concept: Conductance of Electrolytic Solutions > Variation of Conductivity and Molar Conductivity with Concentration
Give reasons for the following:
The transition metals generally form coloured compounds.
Concept: General Properties of the Transition Elements (D-block)
Explain the term Antiseptics
Concept: Drugs and Their Classification
Explain the term osmosis.
Concept: Colligative Properties and Determination of Molar Mass > Osmosis and Osmotic Pressure
Explain the term osmosis.
Concept: Colligative Properties and Determination of Molar Mass > Osmosis and Osmotic Pressure
Calculate the e.m.f. of the following cell at 298 K:
Fe(s) | Fe2+ (0.001 M) | | H+ (0.01 M) | H2(g) (1 bar) | Pt(s)
Given that \[\ce{E^0_{cell}}\] = 0.44 V
[log 2 = 0.3010, log 3 = 0.4771, log 10 = 1]
Concept: Nernst Equation - Introduction
Calculate emf of the following cell at 25°C:
\[\ce{Sn/Sn^2+ (0.001 M) || H+ (0.01 M) | H2_{(g)} (1 bar) | Pt_{(s)}}\]
Given: \[\ce{E^\circ(Sn^2+/sn) = -0.14 V, E^\circ H+/H2 = 0.00 V (log 10 = 1)}\]
Concept: Galvanic or Voltaic Cells - Introduction
Define the Standard enthalpy of combustion.
Concept: Thermochemistry
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
How is the rate of reaction affected if the concentration of B is doubled?
Concept: Factors Influencing Rate of a Reaction
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
Concept: Factors Influencing Rate of a Reaction
Distinguish between Order and Molecularity of reaction.
Concept: Molecularity of Elementary Reactions