Advertisements
Advertisements
प्रश्न
For a reaction A + B ⟶ P, the rate is given by
Rate = k [A] [B]2
What is the overall order of reaction if A is present in large excess?
उत्तर १
If A is present in large excess, then the reaction will be independent of the concentration of A and will be dependent only on the concentration of B. As [B]2 will be the only determining factor in the order of reaction, the overall order of the reaction will be two.
उत्तर २
If A is present in large excess, then the rate of the reaction will be independent of A and will depend only on the concentration of B. The overall rate of the reaction will be 2.
APPEARS IN
संबंधित प्रश्न
Write two factors that affect the rate of reaction.
From the rate expression for the following reaction, determine the order of reaction and the dimension of the rate constant.
\[\ce{CH3CHO_{(g)} -> CH4_{(g)} + CO_{(g)}}\] Rate = k [CH3CHO]3/2
Define the following terms:
Half-life period of reaction (t1/2).
Compounds ‘A’ and ‘B’ react according to the following chemical equation.
\[\ce{A(g) + 2B(g) -> 2C(g)}\]
Concentration of either ‘A’ or ‘B’ were changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. Following results were obtained. Choose the correct option for the rate equations for this reaction.
Experiment | Initial concentration of [A]/mol L–¹ |
Initial concentration of [B]/mol L–¹ |
Initial rate of formation of [C]/mol L–¹ s–¹ |
1. | 0.30 | 0.30 | 0.10 |
2. | 0.30 | 0.60 | 0.40 |
3. | 0.60 | 0.30 | 0.20 |
Why does the rate of any reaction generally decreases during the course of the reaction?
Why molecularity is applicable only for elementary reactions and order is applicable for elementary as well as complex reactions?
Assertion: Order of the reaction can be zero or fractional.
Reason: We cannot determine order from balanced chemical equation.
Use Molecular Orbital theory to determine the bond order in each of species, [He2j+ and [He2]2+?
If the 0.05 molar solution of m+ is replaced by a 0.0025 molar m+ solution, then the magnitude of the cell potential would be
Identify the order of reaction from the following unit for its rate constant:
L mol–1s–1