Advertisements
Advertisements
Question
Answer the following in one or two sentences.
State whether ΔS is positive, negative or zero for the reaction 2H(g) → H2(g). Explain.
Solution
ΔS is negative. Two moles of gaseous H atoms are converted into 1 mole of H2 gas. Thus, a disorder of the system decreases, and hence, entropy decreases, or ∆S is negative.
APPEARS IN
RELATED QUESTIONS
In which of the following, entropy of the system decreases?
Answer the following in one or two sentences.
If the enthalpy change of a reaction is ∆H how will you calculate the entropy of surroundings?
Obtain the relationship between ∆G° of a reaction and the equilibrium constant.
Answer in brief.
What is entropy? Give its units.
Answer the following question.
Although ΔS for the formation of two moles of water from H2 and O2 is –327J K–1, it is spontaneous. Explain.
(Given ΔH for the reaction is –572 kJ).
Answer the following question.
Determine whether the following reaction is spontaneous under standard state conditions.
2H2O(l) + O2(g) → 2H2O2(l)
if ΔH° = 196 kJ, ΔS° = –126 J/K, does it have a cross-over temperature?
A system is changed from an initial state to a final state by a manner such that ∆H = Q. If the change from initial state to final state was made by a different path, then ____________.
For a reversible spontaneous change, ∆S is ____________.
What is the entropy change (in J K−1 mol−1) when one mole of ice is converted into water at 0°C? (The enthalpy change for the conversion of ice to liquid water is 6.0 kJ mol−1 at 0°C)
Which one of the following has ΔS0 greater than zero?
For the following reaction:
\[\ce{Fe2O3_{(s)} + 3CO_{(g)} -> 2Fe_{(s)} + 3CO2_{(g)}}\]; ΔH0 = −29.8 kJ and ΔS0 = 15 J K−1. What is the value of \[\ce{ΔS_{(total)}}\] at 298 K?
Which of the following conditions indicates the reaction is spontaneous?
If ΔH° and ΔS° for the reaction \[\ce{N2O_{4(g)} -> 2NO_{2(g)}}\] is 57.24 kJ and 175.8 JK-1 mol-1 respectively. What is the value of ΔG° for this reaction at 298 K?
Which of following is residual entropy of a substance?
Standard molar entropy is ______.
Calculate the amount of heat liberated during formation of 2. 7 kg of water if heat of formation of water is - 284.5 kJ mol-1.
The equilibrium constant for a reaction is 10, value of ΔG° at 300 K is (R = 8 × 10-3 kJ)
Relation between ΔH and ΔU for the reaction, \[\ce{2SO_{3(g)} -> 2SO_{2(g)} + O_{2(g)}}\] is _______.
Standard enthalpy and standard entropy changes for the oxidation of ammonia at 298 K are −382.64 kJ mol−1 and −145.6 JK−1 mol−1, respectively. Standard Gibb's energy change for the same reaction at 298 K is ______.
Write the correct condition for spontaneity in terms of Gibbs energy.
Identify whether the following pair have larger entropy or not. If yes then Why?
He(g) in a volume of 1 L or He(g) in a volume of 5 L both at 25°C.
Identify whether the following pair have a larger entropy or not. If yes then Why?
O2{g) at 1 atm or O2(g) at 10 atm both at the same temperature.
Write the relationship between Gibbs energy change for a process and total entropy change of system and surroundings.
Calculate ΔG for ΔH = − 110 kJ, ΔS = + 40 J K−1 at 400 K.
ΔH for the reaction is − 110 kJ, and ΔS is + 40 JK−1 at 400 K. The free energy change for the reaction is ______.