Advertisements
Advertisements
Question
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals.
Sulphates
Solution
- Thermal stability-
Sulphates of both group 1 and group 2 metals are stable towards heat. - Solubility-
Sulphates of alkali metals are soluble in water. However, sulphates of alkaline earth metals show varied trends.
BeSO4 Fairly soluble
MgSO4 Soluble
CaSO4 Sparingly soluble
SrSO4 Insoluble
BaSO4 Insoluble
In other words, while moving down the alkaline earth metals, the solubility of their sulphates decreases.
APPEARS IN
RELATED QUESTIONS
Explain why is sodium less reactive than potassium?
Compare the alkali metals and alkaline earth metals with respect to (i) ionization enthalpy (ii) basicity of oxides and (iii) solubility of hydroxides
Compare the solubility and thermal stability of the following compound of the alkali metals with those of the alkaline earth metals.
Nitrates
Compare the solubility and thermal stability of the following compounds of the alkali metals with those of the alkaline earth metals.
Carbonates
Starting with sodium chloride how would you proceed to prepare sodium hydroxide.
Starting with sodium chloride how would you proceed to prepare sodium peroxide.
Starting with sodium chloride how would you proceed to prepare sodium carbonate?
The hydroxides and carbonates of sodium and potassium are easily soluble in water while the corresponding salts of magnesium and calcium are sparingly soluble in water. Explain.
What happens when sodium peroxide dissolves in water?
Comment on the following observation:
The mobilities of the alkali metal ions in aqueous solution are Li+ < Na+ < K+ < Rb+ < Cs+
How would you explain the following observation?
BeO is almost insoluble but BeSO4 in soluble in water.
How would you explain the following observation?
LiI is more soluble than KI in ethanol.
Metal carbonates decompose on heating to give metal oxide and carbon dioxide. Which of the metal carbonates is most stable thermally?
The s-block elements are characterised by their larger atomic sizes, lower ionisation enthalpies, invariable +1 oxidation state and solubilities of their oxosalts. In the light of these features describe the nature of their oxides, halides and oxosalts.
Which of the alkali metals form only the normal oxide, M2O on heating in the air?