English
Karnataka Board PUCPUC Science Class 11

Fluorine reacts with ice and results in the change: HX2O(s)+FX2(g)⟶HF(g)+HOF(g) Justify that this reaction is a redox reaction. - Chemistry

Advertisements
Advertisements

Question

Fluorine reacts with ice and results in the change: \[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Justify that this reaction is a redox reaction.

Short Note

Solution

Let us write the oxidation number of each atom involved in the given reaction above its symbol as:
+1 -2         0              +1 -1        +1 -2 +1
\[\ce{H2O(s) + F2(g) → HF(g) + HOF(g)}\]

Here, we have observed that the oxidation number of F increases from 0 in F2 to +1 in HOF. Also, the oxidation number decreases from 0 in Fto –1 in HF. Thus, in the above reaction, F is both oxidized and reduced.
Hence, the given reaction is a redox reaction.

shaalaa.com
Oxidation Number - Types of Redox Reactions
  Is there an error in this question or solution?
Chapter 8: Redox Reactions - EXERCISES [Page 280]

APPEARS IN

NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 8 Redox Reactions
EXERCISES | Q 8.4 | Page 280

RELATED QUESTIONS

Justify that the following reaction is redox reaction:

\[\ce{CuO(s) + H2(g) → Cu(s) + H2O(g)}\]


Suggest a list of the substances where carbon can exhibit oxidation states from –4 to +4 and nitrogen from –3 to +5.


Identify the substance oxidised, reduced, oxidising agent and reducing agent for the following reaction:

\[\ce{N2H4(l) + 2H2O2(l) → N2(g) + 4H2O(l)}\]


Consider the reactions:

  1. \[\ce{H3PO2(aq) + 4 AgNO3(aq) + 2 H2O(l) → H3PO4(aq) + 4Ag(s) + 4HNO3(aq)}\]
  2. \[\ce{H3PO2(aq) + 2CuSO4(aq) + 2 H2O(l) → H3PO4(aq) + 2Cu(s) + H2SO4(aq)}\]
  3. \[\ce{C6H5CHO(l) + 2[Ag (NH3)2]+(aq) + 3OH–(aq) → C6H5COO–(aq) + 2Ag(s) + 4NH3 (aq) + 2 H2O(l)}\]
  4. \[\ce{C6H5CHO(l) + 2Cu^{2+}(aq) + 5OH–(aq) → No change observed}\]

What inference do you draw about the behaviour of Ag+ and Cu2+ from these reactions?


Arrange the following metals in the order in which they displace each other from the solution of their salts.

Al, Cu, Fe, Mg and Zn.


\[\ce{MnO^{2-}4}\] undergoes disproportionation reaction in acidic medium but \[\ce{MnO^{-}4}\] does not. Give reason.


Assertion (A): The decomposition of hydrogen peroxide to form water and oxygen is an example of disproportionation reaction.

Reason (R): The oxygen of peroxide is in –1 oxidation state and it is converted to zero oxidation state in \[\ce{O2}\] and –2 oxidation state in \[\ce{H2O}\].


Assertion (A): Redox couple is the combination of oxidised and reduced form of a substance involved in an oxidation or reduction half cell.

Reason (R): In the representation \[\ce{E^Θ_{Fe^{3+}/Fe^{2+}}}\] and \[\ce{E^Θ_{Cu^{2+}/Cu}, Fe^{3+}/Fe^{2+}}\] and \[\ce{Cu^{2+}/Cu}\] are redox couples.


Why does fluorine not show disporportionation reaction?


Write redox couples involved in the reactions given.

\[\ce{Cu + Zn^{2+} ->Cu^{2+} + Zn}\]


Write redox couples involved in the reactions given.

\[\ce{Mg + Fe^{2+} -> Mg^{2+} + Fe}\]


Write redox couples involved in the reactions given.

\[\ce{Br2 + 2Cl- -> Cl2 + 2Br-}\]


Write redox couples involved in the reactions given.

\[\ce{Fe + Cd^{2+} -> Cd + Fe^{2+}}\]


Find out the oxidation number of chlorine in the following compounds and arrange them in increasing order of oxidation number of chlorine.

\[\ce{NaClO4, NaClO3, NaClO, KClO2, Cl2O7, ClO3, Cl2O, NaCl, Cl2 , ClO2}\].

Which oxidation state is not present in any of the above compounds?


Which of the following statement is CORRECT for the decomposition reaction of KClO3

\[\ce{2KClO3 → 2KCl +3O2}\]


Which of the following examples does not represent disproportionation?


An acidified manganate solution undergoes disproportionation reaction. The spin-only magnetic moment value of the product having manganese in a higher oxidation state is ______ B.M. (Nearest integer)


The species given below that does NOT show a disproportionation reaction is ______.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×