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Karnataka Board PUCPUC Science Class 11

For the following bond cleavages, use curved-arrows to show the electron flow and classify as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation - Chemistry

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Question

For the following bond cleavages, use curved-arrows to show the electron flow and classify as homolysis or heterolysis. Identify reactive intermediate produced as free radical, carbocation and carbanion.

Short Note

Solution

The bond cleavage using curved-arrows to show the electron flow of the given reaction can be represented as

It is a heterolytic cleavage as the bond breaks in such a manner that the shared pair of electrons remains with one of the fragments. The intermediate formed is a carbocation.

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Fundamental Concepts in Organic Reaction Mechanism - Fission of a Covalent Bond
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Chapter 12: Organic Chemistry - Some Basic Principles and Techniques - EXERCISES [Page 371]

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NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 12 Organic Chemistry - Some Basic Principles and Techniques
EXERCISES | Q 12.16 - (d) | Page 371
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