English

Give Reasons: Sc3+ is Colourless in Aqueous Solution Whereas Ti3+ is Coloured. - Chemistry

Advertisements
Advertisements

Question

Give reasons: Sc3+ is colourless in aqueous solution whereas Ti3+ is coloured.

Solution 1

Sc3+ has no unpaired electron. So, it is colourless, whereas Ti3+ has one unpaired electron. Hence, it is coloured

shaalaa.com

Solution 2

Compounds of transition elements are coloured due to the presence of unpaired electrons in d-orbitals as they show d-d-transition. In Sc+3 there are no d-electrons in Ti+3 there is one d-electrons.

shaalaa.com
  Is there an error in this question or solution?
2017-2018 (March) Delhi Set 1

Video TutorialsVIEW ALL [1]

RELATED QUESTIONS

Why is Sc3+ colourless while Ti3+ coloured? (Atomic number Sc = 21, Ti =22)


Predict which of the following will be coloured in the aqueous solution?

Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Dissociation of H2S is suppressed in acidic medium.


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i) Element with highest second
ionisation enthalpy
(a) \[\ce{Co}\]
(ii) Element with highest
third ionisation enthalpy
(b) \[\ce{Cr}\]
(iii) \[\ce{M}\] in \[\ce{M(CO)6}\] is (c) \[\ce{Cu}\]
(iv) Element with highest heat
of atomisation
(d) \[\ce{Zn}\]
    (e) \[\ce{Ni}\]

A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) and (C) of manganese are formed. Compound (C) reacts with KOH in the presence of potassium nitrate to give compound (B). On heating compound (C) with conc. \[\ce{H2SO4}\] and \[\ce{NaCl}\], chlorine gas is liberated and a compound (D) of manganese along with other products is formed. Identify compounds A to D and also explain the reactions involved.


The orientation of an atomic orbital is governed by


On adding NaOH, solution to the aqueous solution of K2CrO7 the colour of the solution changes from


Consider the following standard electrode potential values:

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V

\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V

What is the cell potential for the redox reaction?


A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.

Based on this information, answer the following question:

  1. Deduce the structural formula of the complex compound.
  2. Write the IUPAC name of the complex compound.
  3. Draw the geometrical isomers of the complex compound.

Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×