English

One Mole of a Gas Expands by 3l Against a Constant Pressure of 3 Atmosphere. Calculate the Work Done - Chemistry

Advertisements
Advertisements

Question

One mole of a gas expands by 3L against a constant pressure of 3 atmosphere. Calculate the work done in -

(a) L.atmosphere

(b) Joules

(c) Calories

Solution

Data: P = 3atm

ΔV = 3L

solution:

W = -PΔV

W = -3 x 3

W = -9L.atm

1L.atm = 101.3J

-9L.atm = -9 × 101.3J

W = -911.7J

4.184J = 1cal

∴ -911.7J = -911.7/4.184

W = -217.9cal

shaalaa.com
  Is there an error in this question or solution?
2013-2014 (March)

APPEARS IN

RELATED QUESTIONS

Absolute entropies of solids, liquids and gases can be determined by

  • Measuring heat capacity of substance at various temperatures
  • Subtracting standard entropy of reactants from products
  • Measuring vibrational motion of molecules
  • Using formula ΔS° = ST° - SO°

Determine whether the reactions with the following ΔH and ΔS values are spontaneous or non-spontaneous. State whether the reactions are exothermic or endothermic.

(a) ΔH = -110kJ, ΔS = + 40JK-1 at 400 K

(b) ΔH = + 40kJ, ΔS = -120JK-1 at 250K


300 M mol of perfect gas occupies 13 L at 320 K. Calculate the work done in joules when the gas expands-

(a) isothermally against a Constant external pressure of 0.20atm.

(b) isothermal and reversible process.

(c) into vaccum until the volume of gas is increased by 3L (R=8.314J mol-1 K-1)


Which of the following pairs is an intensive property?

(A) Density, viscosity

(B) Surface tension, mass

(C) Viscosity, internal energy

(D) Heat capacity, volume


55 L atm of work is obtained when 1.0 mole of an ideal gas is compressed isothermally from
a volume of 28.5 L to 18.5 L, the constant external pressure is

(A) 5.05 atm

(B) 5.5 atm

(C) 0.05 atm

(D) 0.55 atm


For a certain reaction, ∆H = − 50 kJ and ∆S = − 80 J K-1, at what temperature does the
reaction turn from spontaneous to non-spontaneous?

(A) 6.25 K

(B) 62.5 K

(C) 625 K

(D) 6250 K


What is the action of heat on potassium permanganate?


Derive the equation : W = - PextAV


5 moles of helium expand isothermally and reversibly from a pressure 40 × 10-5  N m-2 to 4 × 10-5 N m-2  at 300 K. Calculate the work done, change in internal energy and heat absorbed during the expansion. (R = 8.314 J K-1  mol-1).


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×