Advertisements
Advertisements
Question
The slope in the plot of [R] Vs. time for a zero-order reaction is ______.
Options
`(+"k")/2.303`
`(-"k")/2.303`
−k
+k
Solution
The slope in the plot of [R] Vs. time for a zero-order reaction is −k.
Explanation:
For the reaction, \[\ce{R -> Products}\]
The integrated zero-order rate equation is [R] = −kt + [R0]
Comparing with the equation of a straight line, y = mx + c, if we plot [R] against t, we get a straight line with slope = −k and intercept equal to [R0]·
APPEARS IN
RELATED QUESTIONS
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks in the following table:
Experiment | A/mol L−1 | B/mol L−1 | Initial rate/mol L−1 min−1 |
I | 0.1 | 0.1 | 2.0 × 10−2 |
II | ______ | 0.2 | 4.0 × 10−2 |
III | 0.4 | 0.4 | ______ |
IV | ______ | 0.2 | 2.0 × 10−2 |
Derive integrated rate law for a zero-order reaction \[\ce{A -> Product}\].
For which of the following reaction the units of rate constant and rate of the reaction are same?
Write the rate equation for the reaction `2A + B -> C` if the order of the reaction is zero.
For a zero order reaction will the molecularity be equal to zero? Explain.
For a zero-order reaction, the plot of [A]t vs t is linear with a ______
Write the expression of integrated rate equation for zero order reaction.
If the initial concentration of substance A is 1.5 M and after 120 seconds the concentration of substance A is 0.75 M, the rate constant for the reaction if it follows zero-order kinetics is ______.
What is zeroth order reaction? Derive its integrated rate Law. What are the units of rate constant?
What is zero order reaction?