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What is Hinsberg's reagent? - Chemistry

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Question

What is Hinsberg's reagent?

Chemical Equations/Structures
Short Answer

Solution 1

Hinsberg reagent is also known as benzene sulphonyl chloride \[\ce{(C6H5SO2Cl)}\]. When it reacts with primary and secondary amines, it produces sulphonamides. Allowing secondary and tertiary amines to react with Hinsberg's reagent allows them to be distinguished (benzesulphonyl chloride \[\ce{C6H5SO2Cl}\]). Secondary amines react with Hinsberg's reagent to form an alkali-insoluble product. \[\ce{N}\], \[\ce{N}\]-diethylamine for example, reacts with Hinsberg's reagent to form \[\ce{N}\], \[\ce{N}\]-diethlbenzenesulphonamide, which is insoluble in alkalis. Tertiary amines, on the other hand, are unaffected by Hinsberg's reagent.

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Solution 2

The Hinsberg reagent is a chemical reagent used in organic chemistry for the identification and differentiation of primary, secondary, and tertiary amines. The Hinsberg reagent is typically composed of benzenesulfonyl chloride \[\ce{(C6H5SO2Cl)}\].

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Notes

Students can refer to the provided solutions based on their preferred marks.

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Chapter 13: Amines - Multiple Choice Questions (Type - I) [Page 189]

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