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Why the ground-state electronic configurations of gadolinium and lawrentium are different than expected? - Chemistry

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Question

Why the ground-state electronic configurations of gadolinium and lawrentium are different than expected?

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Solution

Gadolinium and lutetium show different ground-state electronic configurations because the 5d and 4f-orbitals are near to the same energy due to which the next electron goes in 5d-orbital instead of 4forbital. This retains the extra stability achieved when the 4f orbital is half-filled and completely filled respectively. Thus, the 5d orbital contains one electron in the case of gadolinium and lutetium.

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Inner Transition (f-block) Elements: Lanthanoids and Actinoids
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Chapter 8: Transition and Inner transition Elements - Exercises [Page 191]

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Balbharati Chemistry [English] 12 Standard HSC
Chapter 8 Transition and Inner transition Elements
Exercises | Q 3.08 | Page 191
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