The Covalent Bond

A covalent bond is a chemical bond formed when two atoms share their valence electrons to complete their electron octet or duplet. This sharing of electrons allows both atoms to achieve stability. 

• Covalent bonds are typically formed between atoms with similar electronegativities, as they do not tend to transfer electrons.
• Unlike ionic bonds, where electrons are transferred, covalent bonds involve the sharing of valence electrons.
• The shared electrons count toward the outer shell of both atoms, allowing them to fulfil the octet rule (for most atoms) or the duplet rule (for smaller atoms like hydrogen).

(a) Formation of H₂ Molecule (Hydrogen Molecule):

1. Each hydrogen atom has 1 electron in its valence shell.
2. Hydrogen needs 1 more electron to complete its duplet.
3. Two hydrogen atoms share their single electrons, forming a single covalent bond. The duplet of both hydrogen atoms is complete.
4. The molecule is represented as H—H, where the dash represents the covalent bond.

H • + H •  →  H:H  → H—H

Formation of Covalent bond in the H₂ molecule

(b) Formation of H₂O Molecule (Water):

1. Oxygen has 6 valence electrons in its outer shell.
2. It needs 2 more electrons to complete its octet.
3. Each hydrogen atom has 1 valence electron and needs 1 more electron to complete its duplet.
4. The oxygen atom shares 1 electron each with 2 hydrogen atoms, forming two covalent bonds. The octet of the oxygen atom is completed.
5. The duplets of the two hydrogen atoms are also completed.

The molecule is represented as H—O—H.   

Formation of Covalent bond in H₂O molecule

(c) Formation of N₂ Molecule (Nitrogen Molecule):

1. Each nitrogen atom has 5 valence electrons in its outer shell.
2. Nitrogen needs 3 more electrons to complete its octet.
3. Two nitrogen atoms share three pairs of electrons (6 electrons in total) to complete their octets.
4. This forms a triple covalent bond between the two nitrogen atoms. Both nitrogen atoms achieve a stable octet.
5. The molecule is represented as N≡N, where the three dashes represent the triple bond.

Formation of Covalent bond in the N₂ molecule

1. Covalent compounds are generally poor conductors of electricity, as they do not have free ions or electrons.
2. They have low melting and boiling points due to weak intermolecular forces, despite strong covalent bonds.
3. Most covalent compounds are insoluble in water but dissolve in organic solvents like alcohol and benzene.
4. They can exist in all three states of matter: solid, liquid, or gas, depending on their molecular structure.
5. Covalent compounds are typically brittle and not malleable or ductile.
6. They have definite molecular structures with fixed ratios of atoms.
7. Reactions involving covalent compounds are often slower compared to ionic compounds due to the breaking and rearranging of covalent bonds.
8. They may exhibit polar or non-polar properties, depending on the electronegativity difference between the bonded atoms.