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प्रश्न
Arrange water, ethanol and phenol in increasing order of acidity and give reason for your answer.
उत्तर
The increasing order of acidity is ethanol < water < phenol. The phenoxide ion obtained after the removal of a proton is stabilised by resonance whereas the ethoxide ion obtained after the removal of a proton is destabilised by the ‘+I’ effect of the —C2H5 group. Therefore phenol is a stronger acid than ethanol. On the other hand, ethanol is a weaker acid than water because the electron-releasing —C2H5 group in ethanol increases the electron density on oxygen and hence the polarity of the O—H bond in ethanol decreases which results in the decreasing acidic strength. Hence acidic strength increases in the order given above.
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संबंधित प्रश्न
Give simple chemical test to distinguish between Ethanol and Phenol.
Among the following the one which reacts most readily with ethanol is:
Phenol is less acidic than ______.
Phenol can be distinguished from ethanol by the reactions with:
(i) \[\ce{Br2/water}\]
(ii) \[\ce{Na}\]
(iii) Neutral \[\ce{FeCl3}\]
(iv) All the above
What is denatured alcohol?
Suggest a reagent for conversion of ethanol to ethanal.
Arrange the following compounds in increasing order of acidity and give a suitable explanation.
Phenol, o-nitrophenol, o-cresol
Name the enzymes and write the reactions involved in the preparation of ethanol from sucrose by fermentation.
Match the items of column I with items of column II.
| Column I | Column II | |
| (i) | Methanol | (a) Conversion of phenol to o-hydroxysalicylic acid |
| (ii) | Kolbe’s reaction | (b) Ethyl alcohol |
| (iii) | Williamson’s synthesis | (c) Conversion of phenol to salicylaldehyde |
| (iv) | Conversion of 2° alcohol to ketone | (d) Wood spirit |
| (v) | Reimer-Tiemann reaction | (e) Heated copper at 573 K |
| (vi) | Fermentation | (f) Reaction of alkyl halide with sodium alkoxide |
Tonics in general contain
