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How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom. m-Nitrobenzoic acid - Chemistry

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प्रश्न

How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

m-Nitrobenzoic acid

रासायनिक समीकरण/संरचनाएँ

उत्तर

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अध्याय 12: Aldehydes, Ketones and Carboxylic Acids - Exercises [पृष्ठ ३७८]

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एनसीईआरटी Chemistry [English] Class 12
अध्याय 12 Aldehydes, Ketones and Carboxylic Acids
Exercises | Q 14.2 | पृष्ठ ३७८

संबंधित प्रश्न

Identify ‘A' and ‘B’ in the following reaction :

C6H5MgBr + C02 `(`> ‘A’   `(PCl_5)/()`> ‘B’

 


Write the structures of A and B in the following reactions


Name the reagents used in the following reactions:


Show how the following compound can be converted to benzoic acid.

Bromobenzene


Predict the products formed when cyclohexanecarbaldehyde reacts with the following reagent.

Tollens’ reagent


An organic compound (A) (molecular formula C8H16O2) was hydrolysed with dilute sulphuric acid to give a carboxylic acid (B) and an alcohol (C). Oxidation of (C) with chromic acid produced (B). (C) on dehydration gives but-1-ene. Write equations for the reactions involved.


How will you prepare the given compound from benzene? You may use any inorganic reagent and any organic reagent having not more than one carbon atom.

Phenylacetic acid


How is methoxy benzene prepared from carbolic acid?


Name the reagents used in the following reactions:


Which is the most suitable reagent for the following conversion?

\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]


Through which of the following reactions number of carbon atoms can be increased in the chain?

(i) Grignard reaction

(ii) Cannizaro’s reaction

(iii) Aldol condensation

(iv) HVZ reaction


Match the reactions given in Column I with the suitable reagents given in Column II.

Column I
(Reactions)
Column II
(Reagents)
(i) Benzophenone Diphenylmethane (a) \[\ce{LiAlH4}\]
(ii) Benzaldehyde 1-Phenylethanol (b) \[\ce{DIBAL-H}\]
(iii) Cyclohexanone Cyclohexanol (c) \[\ce{Zn(Hg)/Conc. HCl}\]
(iv) Phenyl benzoate Benzaldehyde (d) \[\ce{CH3MgBr}\]

Assertion: Aldehydes and ketones, both react with Tollen’s reagent to form silver mirror.

Reason: Both, aldehydes and ketones contain a carbonyl group.


Substitution of one alkyl group by replacing hydrogen of primary amines


Match List - I with List - II.

List - I List - II
(a) \[\ce{->[CO,HCl][Anhyd. AlCl3/CuCl]}\] (i) Hell-Volhard-Zelinsky reaction
(b)
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\
||\phantom{.................}\\
\ce{R - C - CH3 + NaOX ->}
\end{array}\]
(ii) Gattermann-Koch reaction
(c) \[\ce{R - CH2 - OH + R'COOH ->[Conc. H2SO4]}\] (iii) Haloform reaction
(d) \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] (iv) Esterification

Choose the correct answer from the options given below.


Y is:


A compound 'X' with molecular formula C3H8O can be oxidised to a compound 'Y' with the molecular formula C3H6O2 'X' is most likely to be ______.


Hex-4-ene-2-ol on treatment with PCC gives 'A'. 'A' on reaction with sodium hypoiodite gives 'B', which on further heating with soda lime gives 'C. The compound 'C' is ______.


Fill in the blanks by choosing the appropriate words from those given in the brackets:

[stable, low, aldehyde, unstable, 6, 4, ethane, Clemmensen’s, 2, 3, carboxylic acid, high, propane, Rosenmund's]

The primary alcohols are easily oxidised first into ______ and then into ______.


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