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प्रश्न
Identify the order of reaction from the following unit for its rate constant:
L mol–1s–1
उत्तर
The unit L mol–1sec–1 for rate constant is the unit of second-order reaction.
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संबंधित प्रश्न
Write molecularity of the following reaction:
2NO(g)+O2(g)→2NO2(g)
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(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.
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\[\ce{C2H5Cl_{(g)} -> C2H4_{(g)} + HCl_{(g)}}\] Rate = k [C2H5Cl]
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Read the following passage and answer the questions that follow:
The rate of reaction is concerned with decrease in the concentration of reactants or increase in the concentration of products per unit of time. It can be expressed as instantaneous rate at a particular instant of time and average rate over a large interval of time. A number of factors such as temperature, concentration of reactants, catalyst affect the rate of reaction. Mathematical representation of rate of a reaction is given by rate law: Rate = k[A]x [B]y x and y indicate how sensitive the rate is to change in concentration of A and B. Sum of x + y gives the overall order of a reaction. |
- What is the effect of temperature on the rate constant of a reason? [1]
- For a reaction \[\ce{A + B → Product}\], the rate law is given by, Rate = k[A]2 [B]1/2. What is the order of the reaction? [1]
- How order and molecularity are different for complex reactions? [1]
- A first-order reaction has a rate constant 2 × 10–3 s–1. How long will 6 g of this reactant take to reduce to 2 g? [2]
OR
The half-life for radioactive decay of 14C is 6930 years. An archaeological artifact containing wood had only 75% of the 14C found in a living tree. Find the age of the sample.
[log 4 = 0.6021, log 3 = 0.4771, log 2 = 0.3010, log 10 = 1] [2]
Assertion (A): Order of reaction is applicable to elementary as well as complex reactions.
Reason (R): For a complex reaction, molecularity has no meaning.