Advertisements
Advertisements
प्रश्न
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals:
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (ii) | (a) `n = 3, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iii) | (a) `n = 4, l = 1, m_l = 1, m_s = + 1/2` |
| (b) `n = 3, l = 2, m_l = 1, m_s = + 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
उत्तर
| (i) | (a) `n = 3, l = 2, m_l = -2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = -1, m_s = - 1/2` | |
| (iv) | (a) `n = 3, l = 2, m_l = +2, m_s = - 1/2` |
| (b) `n = 3, l = 2, m_l = +2, m_s = + 1/2` |
Explanation:
In a multi-electron atomic system the energy of an electron depends not only on its principal quantum number (shell), but also on its azimuthal quantum number (subshell). Electrons having the same shells and same subshells have the same energy and they are known as degenerate orbitals.
APPEARS IN
संबंधित प्रश्न
Choose the correct option.
“No two electrons in the same atoms can have identical set of four quantum numbers”. This statement is known as -
State and explain Pauli’s exclusion principle.
State the order of filling atomic orbitals following Aufbau principle.
Explain the anomalous behaviour of copper.
Explain the anomalous behaviour of chromium.
Write condensed orbital notation of electronic configuration of the following element:
Chlorine (Z = 17)
The arrangement of orbitals on the basis of energy is based upon their (n + l) value. Lower the value of (n + l), lower is the energy. For orbitals having same values of (n + l), the orbital with lower value of n will have lower energy.
Based upon the above information, solve the questions given below:
Which of the following orbitals has the lowest energy?
4d, 4f, 5s, 5p
Match the quantum numbers with the information provided by these.
| Quantum number | Information provided |
| (i) Principal quantum number | (a) orientation of the orbital |
| (ii) Azimuthal quantum number | (b) energy and size of orbital |
| (iii) Magnetic quantum number | (c) spin of electron |
| (iv) Spin quantum number | (d) shape of the orbital |
Match the following
| (i) Photon | (a) Value is 4 for N shell |
| (ii) Electron | (b) Probability density |
| (iii) ψ2 | (c) Always positive value |
| (iv) Principal quantum number n | (d) Exhibits both momentum and wavelength |
In the case of R, S configuration the group having the highest priority is ______.
