Advertisements
Advertisements
प्रश्न
Solutions of two electrolytes ‘A’ and ‘B’ are diluted. The Λm of ‘B’ increases 1.5 times while that of A increases 25 times. Which of the two is a strong electrolyte? Justify your answer. Graphically show the behavior of ‘A’ and ‘B’.
उत्तर
B is a strong electrolyte. The molar conductivity increases slowly with dilution as there is no increase in number of ions on dilution as strong electrolytes are completely dissociated.
APPEARS IN
संबंधित प्रश्न
State Kohlrausch’s law of independent migration of ions.
The molar conductivity of cation and anion of salt BA are 180 and 220 mhos respectively. The molar conductivity of salt BA at infinite dilution is_____________ .
(a) 90 mhos.cm2
(b) 110 mhos.cm2.mol-1
(c) 200 mhos.cm2.mol-1
(d) 400 mhos.cm2.mol-1
Why conductivity of an electrolyte solution decreases with the decrease in concentration ?
Define the following terms: Molar conductivity (⋀m)
Why on dilution the m Λm of \[\ce{CH3COOH}\] increases very fast, while that of \[\ce{CH3COONa}\] increases gradually?
The molar conductance of NaCl, HCl, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm2 mol−1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.
Given below are two statements:
Statements I: The limiting molar conductivity of KCl (strong electrolyte) is higher compared to that of CH3COOH (weak electrolyte).
Statement II: Molar conductivity decreases with decrease in concentration of electrolyte.
In the light of the above statements, choose the most appropriate answer from the options given below:
The solubility of Co2[Fe(CN)6] in water at 25°C from the following data:
Conductivity of saturated solution of Co2[Fe(CN)6] = 2.06 × 10−6 ohm−1 cm−1 and that of water = 4.1 × 10−7 ohm−1 cm−1. The ionic molar conductivities of Co2+ and [Fe(CN)6]4− are 86 and 444 ohm−1 cm2 mol−1 respectively, is ______ × 10−6 mol/L.
The specific conductance of 2.5 × 10-4 M formic acid is 5.25 × 10-5 ohm-1 cm-1. Calculate its molar conductivity and degree of dissociation.
Given `λ°_("H"^+)` = 349.5 ohm-1 cm2 mol-1 and
`λ°_("HCOO"^-) = 50.5 " ohm"^-1 "cm"^2 "mol"^-1`
Discuss the variation of conductivity and molar conductivity with concentration.
