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State the various statements of the second law of thermodynamics. - Chemistry

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प्रश्न

State the various statements of the second law of thermodynamics.

संक्षेप में उत्तर

उत्तर

  1. Entropy statement: Whenever a spontaneous process takes place, it is accompanied by an increase in the total entropy of the universe”.
  2. Kelvin-Planck statement: It is impossible to take heat from a hotter reservoir and convert it completely into work by a cyclic process without transferring a part of heat to a cooler reservoir.
  3. Efficiency statement: Even an ideal, frictionless engine cannot convert 100% of its input heat into work.
    Efficiency = `("T"_1 - "T"_2)/"T"_1`
    % Efficiency = `[("T"_1 - "T"_2)/"T"_1] xx 100`
    % Efficiency = `["Output"/"Input"] xx 100`
    % Efficiency < 100%
  4. Clausius statement: Heat flows spontaneously from hot objects to cold objects and to get it to flow in the opposite direction, we have to spend some work.
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Various Statements of the Second Law of Thermodynamics
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अध्याय 7: Thermodynamics - Evaluation [पृष्ठ २२५]

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सामाचीर कलवी Chemistry - Volume 1 and 2 [English] Class 11 TN Board
अध्याय 7 Thermodynamics
Evaluation | Q II. 20. | पृष्ठ २२५

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