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Write Short Notes on the Following Carbylamine Reaction - Chemistry

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प्रश्न

Write short notes on the following Carbylamine reaction

उत्तर

Carbylamine reaction :- Carbylamine reaction is used as a test for the identification of primary amines. When aliphatic and aromatic primary amines are heated with chloroform and ethanolic potassium hydroxide, carbylamines (or isocyanides) are formed. These carbylamines have very unpleasant odours. Secondary and tertiary amines do not respond to this test.

For example,

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अध्याय 13: Amines - Exercises [पृष्ठ ४०१]

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एनसीईआरटी Chemistry [English] Class 12
अध्याय 13 Amines
Exercises | Q 7 (i) | पृष्ठ ४०१

संबंधित प्रश्न

Arrange the following in increasing order of their basic strength in aqueous solution:

\[\ce{CH3NH2, (CH3)3N, (CH3)2NH}\]


Arrange the following:

Aniline, p-nitroaniline, p-methylaniline - in the increasing order of their basic strength


Write the chemical equations involved when aniline is treated with the following reagents: HCI


Arrange the following:

 In increasing order of basic strength:

C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2


Arrange the following:

In increasing order of basic strength: C6H5NH2, C6H5NHCH3, C6H5CH2NH2.

 


Arrange the following:

In decreasing order of basic strength in gas phase: C2H5NH2, (C2H5)2NH, (C2H5)3N and NH3

 


The most reactive amine towards dilute hydrochloric acid is:


The correct decreasing order of basic strength of the following species is ______.

\[\ce{H2O, NH3, OH-, NH^{-}2}\]


Explain why \[\ce{MeNH2}\] is stronger base than \[\ce{MeOH}\]?


Account for the following:

Acylation of aniline is carried out in the presence of pyridine.


When methyl iodide is heated with ammonia, what is the product obtained?


Which of the following statement is true about methyl amine?


Give reasons for the following observation:

pKb of aniline is lower than the m-nitroaniline.


Among the following, which has the highest value of pKb?


Arrange the decreasing order of pKb values.

\[\ce{C6H5NH2, C6H5NHCH3, C6H5CH2NH2, CH3NH2, NH3}\]


State one reason for the following:

Alkylamine is soluble in water, whereas arylamine is insoluble in water.


The correct order of the increasing basic nature of Ammonia, Methylamine and Aniline is:


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