Advertisements
Advertisements
प्रश्न
Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?
उत्तर
Allyl chloride shows high reactivity because the carbocation formed by hydrolysis is stabilised by resonance while no such stabilisation of carbocation exists in the case of n-propyl chloride.
संबंधित प्रश्न
What happens when \[\ce{CH3 - Br}\] is treated with KCN?
Write the final product(s) in each of the following reactions:
The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.
Write the product formed on reaction of D-glucose with Br2 water.
What is Grignard reagent?
Write chemical equation in support of your answer.
Out of Cl and
CH2- Cl, which one is more reactive towards nucleophilic substitution reaction and why?
Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.
Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.
Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?
(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]
\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]
The number of carbon atoms present in the product B is:
Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.