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Allyl chloride is hydrolysed more readily than n-propyl chloride. Why? - Chemistry

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प्रश्न

Allyl chloride is hydrolysed more readily than n-propyl chloride. Why?

टीपा लिहा

उत्तर

Allyl chloride shows high reactivity because the carbocation formed by hydrolysis is stabilised by resonance while no such stabilisation of carbocation exists in the case of n-propyl chloride.

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पाठ 10: Haloalkanes and Haloarenes - Exercises [पृष्ठ १४४]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 10 Haloalkanes and Haloarenes
Exercises | Q III. 65. | पृष्ठ १४४

व्हिडिओ ट्यूटोरियलVIEW ALL [1]

संबंधित प्रश्‍न

What happens when \[\ce{CH3 - Br}\] is treated with KCN?


Write the final product(s) in each of the following reactions:


The presence of nitro group (−NO2) at o/p positions increases the reactivity of haloarenes towards nucleophilic substitution reactions.


Write the product formed on reaction of D-glucose with Br2 water.


What is Grignard reagent?


Write chemical equation in support of your answer. 
 Out of   Cl and  CH2- Cl,  which one is more reactive towards nucleophilic substitution reaction and why? 


Assertion: Presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.


Which of the following compounds will give racemic mixture on nucleophilic substitution by \[\ce{OH-}\] ion?

(a) \[\begin{array}{cc}
\phantom{}\ce{CH3 - CH - Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(b) \[\begin{array}{cc}
\phantom{..}\ce{Br}\\
\phantom{}|\\
\phantom{}\ce{CH3 - C - CH3}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]

 

(c) \[\begin{array}{cc}
\phantom{....}\ce{CH3 - CH - CH2Br}\\
\phantom{}|\\
\phantom{....}\ce{C2H5}\phantom{}
\end{array}\]


\[\ce{C6H12O6 ->[(Zymase)] A ->[NaOH][\Delta] B + CHI3}\]

The number of carbon atoms present in the product B is:


Why haloarenes are not reactive towards nucleophilic substitution reaction? Give two reactions.


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