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प्रश्न
Answer the following.
Explain reverse osmosis.
उत्तर
i. If a pressure larger than the osmotic pressure is applied to the solution side, then pure solvent from the solution passes into pure solvent side through the semipermeable membrane. This phenomenon is called reverse osmosis.
ii. For example, consider fresh water salt water separated by a semipermeable membrane. When the pressure larger than the osmotic pressure of a solution is applied to solution, pure water from salty water passes into fresh pure water through the membrane. Thus, the direction of osmosis can be reversed by applying a pressure larger than the osmotic pressure.
iii. The schematic set up for reverse osmosis is as follows:
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संबंधित प्रश्न
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Which of the following is not a colligative property?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Which of the following 0.1 M will aqueous solutions exert highest osmotic pressure?
(a) `Al_2(SO_4)_3`
(b) `Na_2SO_4`
(c) `MgCl_2`
(d) KCl
Define Semipermeable membrane
Calculate the mass of a compound (molar mass = 256 g mol−1) to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (Kf = 5.12 K kg mol−1).
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
What are isotonic and hypertonic solutions?
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
Which of the following statements is applicable for 0.1 M urea solution and 0.1 M sucrose solution?
What are hypertonic solutions?
Explain the osmotic pressure of a solution with the help of a thistle tube.
Explain the phenomenon of osmosis.
Which of the following is a colligative property?
At constant temperature the osmotic pressure of a solution is ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is:
Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/litre will be:
Isotonic solutions must have the same:
(i) solute
(ii) density
(iii) elevation in boiling point
(iv) depression in freezing point
In isotonic solutions:
(i) Solute and solvent both are same.
(ii) Osmotic pressure is same.
(iii) Solute and solvent may or may not be same.
(iv) Solute is always same solvent may be different.
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
Match the items given in Column I and Column II.
Column I | Column II |
(i) Saturated solution | (a) Solution having same osmotic pressure at a given temperature as that of given solution. |
(ii) Binary solution | (b) A solution whose osmotic pressure is less than that of another. |
(iii) Isotonic solution | (c) Solution with two components. |
(iv) Hypotonic solution | (d) A solution which contains maximum amount of solute that can be dissolved in a given amount of solvent at a given temperature. |
(v) Solid solution | (e) A solution whose osmotic pressure is more than that of another. |
(vi) Hypertonic solution | (f) A solution in solid phase. |
Discuss biological and industrial importance of osmosis.
Osmotic pressure of a solution increases if
Which of the following colligative property can provide molar mass of proteins (or polymers or colloids) with greatest precision?
In Isotonic solution
The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.
Osmotic pressure of a solution containing 2 g dissolved protein per 300 cm3 of solution is 20 mm of Hg at 27°C. The molecular mass of protein is ______.
The following solutions were prepared by dissolving 10 g of glucose \[\ce{(C6H12O6)}\] in 250 ml of water (P1), 10 g of urea \[\ce{(CH4N2O)}\] in 250 ml of water (P2) and 10 g of sucrose \[\ce{(C12H22O11}\]) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is ______
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
Isotonic solutions are the solutions having the same ______.
A solution containing 10 g glucose has osmotic pressure 3.84 atm. If 10 g more glucose is added to the same solution, what will be its osmotic pressure? (Temperature remains constant)
Define osmotic pressure (π).
Prove that: M2 = `(W_2RT)/(πV)`.
Write the condition of reverse osmosis.