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प्रश्न
Explain the phenomenon of osmosis.
उत्तर
- The net spontaneous flow of solvent molecules into the solution or from more dilute solution to more concentrated solution through a semipermeable membrane is called osmosis.
- When a solution and pure solvent or two solutions of different concentrations are separated by a semipermeable membrane, the solvent molecules pass through the membrane. However, the rate of passage of solvent molecules into the solution or from a more dilute solution to more concentrated solution is found to be greater than the rate in the reverse direction. This is favourable since the vapour pressure of the solvent is greater than that of the solution.
- As a result of osmosis, the amount of liquid on the pure solvent side or more dilute solution side decreases. Consequently, the amount of liquid on the other side increases. This results in decrease of the concentration of solution.
Osmosis
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संबंधित प्रश्न
Determine the osmotic pressure of a solution prepared by dissolving 2.5 × 10−2 g of K2SO4 in 2L of water at 25°C, assuming that it is completely dissociated.
(R = 0.0821 L atm K−1 mol−1, Molar mass of K2SO4 = 174 g mol−1)
Which of the following is not a colligative property?
What happens when the external pressure applied becomes more than the osmotic pressure of solution?
Blood cells are isotonic with 0.9% sodium chloride solution. What happens if we place blood cells in a solution containing
(i) 1.2% sodium chloride solution?
(ii) 0.4% sodium chloride solution?
A solution containing 15 g urea (molar mass = 60 g mol–1) per litre of solution in water has the same osmotic pressure (isotonic) as a solution of glucose (molar mass = 180 g mol–1) in water. Calculate the mass of glucose present in one litre of its solution.
At 300 K, 36 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic pressure of the solution is 1.52 bars at the same temperature, what would be its concentration?
Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic pressure is 0.75 atm at 27°C.
Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 liter of water at 25°C, assuming that it is completely dissociated.
Calculate the mass of NaCl (molar mass = 58.5 g mol−1) to be dissolved in 37.2 g of water to lower the freezing point by 2°C, assuming that NaCl undergoes complete dissociation. (Kf for water = 1.86 K kg mol−1)
Define the following term:
isotonic solution
Define the following term:
hypertonic solution
Define the following term:
hypotonic solution
Choose the most correct option.
A living cell contains a solution which is isotonic with 0.3 M sugar solution. What osmotic pressure develops when the cell is placed in 0.1 M KCl solution at body temperature?
Choose the most correct option.
The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume)________.
Answer the following in one or two sentences.
What is osmotic pressure?
Answer the following in one or two sentences.
A solution concentration is expressed in molarity and not in molality while considering osmotic pressure. Why?
Answer the following.
What are isotonic and hypertonic solutions?
Answer the following.
A solvent and its solution containing a nonvolatile solute are separated by a semipermeable membrane. Does the flow of solvent occur in both directions? Comment giving a reason.
Answer the following.
The osmotic pressure of CaCl2 and urea solutions of the same concentration at the same temperature are respectively 0.605 atm and 0.245 atm, calculate van’t Hoff factor for CaCl2.
Answer the following.
Explain reverse osmosis.
An aqueous solution of a certain organic compound has a density of 1.063 g mL-1 , osmotic pressure of 12.16 atm at 25 °C and a freezing point of 1.03 °C. What is the molar mass of the compound?
Explain the term osmosis.
Two solutions have different osmotic pressures. The solution of higher osmotic pressure is called ____________.
At constant temperature the osmotic pressure of a solution is ____________.
20 g of a substance were dissolved in 500 mL of water and the osmotic pressure of the solution was found to be 600 mm of mercury at 15°C. The molecular weight of the substance is:
The average osmotic pressure of human blood is 7.8 bar at 37°C. What is the concentration of an aqueous NaCl solution that could be used in the blood stream?
The temperature at which 10% aqueous solution of (W/V) of glucose will show the osmotic pressure of 16.4 atoms is: (R = 0.082 L atom K−1 mol−1)
Which of the following statements is false?
Discuss biological and industrial importance of osmosis.
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Osmotic pressure of a solution increases if
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Which one of the following is a colligative property?
The vapour pressure of water is 12.3 k pa at 300 k. Calculated the vapour pressure of molal solution in it.
The following solutions were prepared by dissolving 10 g of glucose \[\ce{(C6H12O6)}\] in 250 ml of water (P1), 10 g of urea \[\ce{(CH4N2O)}\] in 250 ml of water (P2) and 10 g of sucrose \[\ce{(C12H22O11}\]) in 250 ml of water (P3). The right option for the decreasing order of osmotic pressure of these solutions is ______
Derive an expression to calculate molar mass of non-volatile solute by osmotic pressure measurement.
Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is proportional to the molality.
Determine the osmotic pressure of a solution prepared by dissolving 2.32 × 10−2 g of K2SO4 in 2L of solution at 25°C assuming that K2SO4 is completely dissociated.
(R = 0.082 L atm K−1 mol, Molar mass K2SO4 = 174 g mol−1)
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Prove that: M2 = `(W_2RT)/(πV)`.
Name the four colligative properties that are oftently used for determination of molecular mass.
How will you determine molar mass of solute from osmotic pressure?
Write the condition of reverse osmosis.
