Advertisements
Advertisements
प्रश्न
Answer the following in one or two sentences.
For the reaction,
\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`
What is the change in rate if concentrations of both reactants are doubled?
उत्तर
For the reaction
\[\ce{CH3Br_{(aq)} + Br^-_{ (aq)} -> CH3OH_{ (aq)} + Br^-_{ (aq)}}\]
Rate = k`["CH"_3"Br"]["OH"^-]`
If concentrations of `"CH"_3"Br"` and `"OH"^-` are doubled, rate will increase by a factor of 4.
APPEARS IN
संबंधित प्रश्न
What is the half life of a first order reaction if time required to decrease concentration of reactant from 0.8 M to 0.2 M is 12 h?
Choose the most correct option.
The elementary reaction \[\ce{O3_{(g)} + O_{(g)} -> 2O2_{(g)}}\] is ___________.
Choose the most correct option.
Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.
Answer the following in brief.
For the reaction 2A + B → products, find the rate law from the following data.
[A]/M | [B]/M | rate/M s-1 |
0.3 | 0.05 | 0.15 |
0.6 | 0.05 | 0.30 |
0.6 | 0.2 | 1.20 |
Write four key points about order of reaction.
A reaction occurs in the following steps:
Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)
Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)
- Write the equation of overall reaction.
- Write the rate law.
- Identify reaction intermediate.
In a first-order reaction A → B, 60% of a given sample of a compound decomposes in 45 mins. What is the half-life of reaction? Also, write the rate law equation for the above first-order reaction.
The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.
For the non-stoichiometric reaction
\[\ce{2A + B -> C + D}\], the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial concentration (A) |
Initial concentration (B) |
Initial rate of formation of C (mol dm−3 s−1) |
0.1 M | 0.1 M | 1.2 × 10−3 |
0.1 M | 0.2 M | 1.2 × 10−3 |
0.2 M | 0.1 M | 2.4 × 10−3 |
The rate law for the formation of C is:
For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.
For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.
The order of the reaction occurring by following mechanism should be:
(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]
(ii) \[\ce{A + B2 -> AB2 (fast)}\]
The rate law for the reaction \[\ce{A + B + C -> Product}\] is expressed as Rate = k[A]2 [B]1 [C]0. What is the overall order of the reaction?
The rate law for the reaction \[\ce{2NO_{(g)} + O2_{(g)} -> 2NO2_{(g)}}\] is rate = k[NO]2 [O2] , then which among the following statement is correct?
In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?
The reaction \[\ce{A + B -> P}\], is second order in A and first order in B. What is the rate law for the reaction?
In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.
What is the order of reaction for decomposition of gaseous acetaldehyde?
In the reaction \[\ce{2SO_{2_{(g)}} O_{2_{(g)}} -> 2SO_{3_{(g)}}}\], the rate of disappearance of SO2 is 1.28 × 10-5 M/s. What is the rate of appearance of SO3?
For the reaction \[\ce{2A + B -> 3C + D}\], which among the following is NOT the correct rate law expression?
For the reaction \[\ce{4NH3 + 5O2 -> 4NO + 6H2O}\], the rate of disappearance of NH3 is 3.6 × 10-3 M/s. What is the rate of formation of water?
Which of the following statement is not true for a reaction having rate law r = k[H2][I2]?
The correct order of raaii of F, F-, O and O2- is ______.
Write the rate law for the following reaction:
A reaction that is second order in NO and first order in Br2.
The rate constant of a reaction ______.
For the reaction A + B → P.
If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.