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प्रश्न
Observe the following and answer the question given below.
Can it react by SN1 mechanism? Justify your answer.
उत्तर
It will not react by SN1 mechanism. The bond between sp2 hybridized carbon atom and halogen is a strong bond. Also, the electrons of the –X atom are in conjugation with the π bond. Thus, C – X bond acquires a double bond character. Thus, when nucleophile approaches the sp2 carbon, it gets repelled by the π-electrons of the double bond.
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संबंधित प्रश्न
from the following pair would undergo SN2 faster from the other?
a. 
b. 
Name the reagent used to bring about the following conversion.
Bromoethane to ethoxyethane
Give reasons:
Haloarenes are less reactive than haloalkanes.
Distinguish between SN1 and SN2 mechanism of substitution reaction.
Major product of the following reaction is _______________
\[\ce{CH3-CH2-Mg-Br + NH3 ->?}\]
Explain the factors affecting SN1 and SN2 mechanism.
Explain aqueous alkaline hydrolysis of tert. butyl bromide.
Which of the following is least reactive towards nucleophilic addition?
Nitroalkanes are obtained in laboratory from primary or secondary alkyl halides by the action of ______.
Which one is most reactive towards nucleophilic addition reaction?
Which of the following carbocation is the most stable?
Identify 'B' in the following reaction.
\[\ce{2-Bromobutane ->[KOH alc.][\Delta] A ->[HI] B}\]
Write the product formed when alkyl halide reacts with silver nitrite.
The order of reactivities of the following alkyl halides for an SN2 reaction is ______.
The order of reactivity of the given haloalkanes towards nucleophiles is:
Complete the following reaction giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/dry ether]A}\\
|\phantom{..................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Observe the following and answer the questions given below:
Name the type of halogen derivative.
Observe the following and answer the question given below:
Can react by SN1 mechanism? Justify your answer.
Discuss β - elimination reaction.
Complete the following reaction sequences by writing the structural formulae of the organic compounds 'A', 'B' and 'C'.
\[\ce{2-Bromobutan ->[alc. KOH] A ->[][Br2] B ->[][NANH2] C}\]
What is the action of following on ethyl bromide?
alcoholic sodium hydroxide
Complete the reaction:
\[\ce{CH3CH2Cl ->[AgCN][alc.\Delta]}\] ?
Complete the following reaction, giving a major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}
\end{array}\]
Give a reason for the following:
Ethoxy ethane with conc. HI at 373 K gives C2H5OH and CH3I but not CH3OH and C2H5I.
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl->[Na/ dry ether]A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{................}\\
\end{array}\]
Complete the following reaction giving major product.
\[\begin{array}{cc}
\ce{CH3}\phantom{.................}\\
|\phantom{...................}\\
\ce{CH3 - C - CH2 - Cl ->[Na/dry ether] A}\\
|\phantom{...................}\\
\ce{CH3}\phantom{.................}\\
\end{array}\]
