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प्रश्न
State any four characteristics of a homologous series
State two characteristics of a homologous series.
उत्तर
Characteristics of a homologous series:
- Each member of the series differs from the preceding one by the addition of a -CH2 group and by 14 a.m.u.
- All members of a homologous series share the general formula.
Example: The general formula for alkane is CnH2n+2 and alkene is CnH2n. - The physical properties of the members show a gradation in properties as the molecular mass increases.
- The chemical properties also show a gradient similarity.
Example: Methane and ethane react with chlorine to form methyl chloride and ethyl chloride, respectively.
CH4 + Cl2 → CH3Cl
C2H6 + Cl2 → C2H5Cl - All members of a homologous series can be prepared by the same general method of preparation.
Example: Alcohols can be prepared from alkyl halides.
`CH_3Br+KOH " Boil"/""CH_3OH+KBr`
`C_2H_5Br+KOH " Boil"/""C_2H_5OH+KBr`
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संबंधित प्रश्न
What is a homologous series?
Write the next homologue of the following: C4H6
What is meant by homologous series of carbon compounds?
Write the molecular formula of two consecutive members of homologous series of aldehydes. State which part of these compounds determines their
- physical and
- chemical properties
Fill in the following blank with suitable word:
Carbon compounds have usually ... melting points and boiling points because they are ...... in nature.
What is the next higher homologue of methanol (CH3OH)?
What is the difference between two consecutive homologues:
(1) in terms of molecular mass?
(2) in terms of number and kind of atoms per molecule?
Write the molecular formula of the third member of the homologous series of carbon compounds with general formula CnHO2n+1OH.
Write the name and molecular formula of the first member of the homologous series of alkynes.
Why homologous series of carbon compounds are so called? Write chemical formula of two consecutive members of a homologous series and state the part of these compounds that determines their (i) physical properties, and (ii) chemical properties.
Give three points to differentiate between saturated and unsaturated
hydrocarbons.
Copy and complete the following table which relates to three homologus series of hydrocarbons:
| General formula | CnH2n | CnH2n-2 | CnH2n+2 |
| IUPAC name of the homologus series | |||
| Characteristic bond type | Single bonds | ||
| IUPAC name of the first member of the series | |||
| Type of reaction with chlorine | Addition |
Complete the correlation:
Alkene : C = C :: Alkyne: _______.
The phenomenon in which compounds having different structural formulae have the same molecular formula is called _______.
Cyclohexane : Cyclic hydrocarbon : : Isobutylene : _______
Saturated hydrocarbon : Single bond : : Unsaturated hydrocarbon : _______
As one ascends in any homologous series, physical properties change gradually.
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
Which of the following pairs can be the successive members of a homologous series?
What is called homologous series? Give any three of its characteristics?
A carbon compound ‘A’ having melting point 156K and boiling point 351K, with molecular formula C2H6O is soluble in water in all proportions.
- Identify ‘A’ and draw its electron dot structure.
- Give the molecular formulae of any two homologues of ‘A’.
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H6.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
Consider the carbon compounds having following molecular formula:
(i) C2H2 (ii) C2H5 (iii) C3H7OH (iv) C2H6COOH (v) CH3CHO
- Identify which one of the above compounds, is a member of aldehyde series.
- Write the general formula of the series to which compound C2H2 belongs.
- Which one of the above compounds has triple bonds between carbon-carbon atoms?
- Write the molecular formula of the first member of the homologous series to which the compound C3H7OH belongs.
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H8.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
Name the following:
Group of organic compounds where the successive members follow a regular structural pattern, successive compounds differ by a 'CH2' group.
