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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Structure Of a Noble Gas Species Which is Isostructural Bro−3 - Chemistry

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प्रश्न

Give the formula and describe the structure of a noble gas species which is isostructural with:

`BrO_3^(-)`

उत्तर १

XeO3 is isostructural to `BrO_3^(-)` and has a pyramidal molecular structure.

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उत्तर २

In Br03 ion the central Br atom has 8 valence electrons (7 +1). Out of these, it shares 4 with two atoms of O forming Br = O bonds. Out of the remaining four .electrons, 2 are donated to the third O atom which accounts for its negative charge. The remaining 2 electrons constitute one lone pair. In order to minimise the force of repulsion, the structure of Br03 ion must be pyramidal. Br03 ion has (7 + 3 x 6 + 1) = 26 valence electrons and is isoelectronic as well as iso-structural with noble gas species Xe03 which has also 26(8 + 3 x 6) electrons.

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पाठ 7: The p-block Elements - Exercises [पृष्ठ २०८]

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एनसीईआरटी Chemistry [English] Class 12
पाठ 7 The p-block Elements
Exercises | Q 38.3 | पृष्ठ २०८
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