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प्रश्न
What are Homoleptic complexes?
उत्तर
The complex compounds in which all the ligand which are connected with central atom are same or identical are called homoleptic complexes. For example: [Ni(CO4], [Co(NH3)6]+3.
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संबंधित प्रश्न
Classify the following ligands into monodentate and polydentate —
- Ammonia
- Carbon monoxide
- Ethylene diamine
- Ethylene diamine tetra acetate ion
Write IUPAC names of the following compounds
The coordination number of the central ion may be obtained from:
In which of the following compounds the oxidation state of the nickel atom is 0?
Which of the following complexes are homoleptic?
(i) \[\ce{[Co(NH3)6]^{3+}}\]
(ii) \[\ce{[Co(NH3)4 Cl2]^{+}}\]
(iii) \[\ce{[Ni(CN)4]^{2-}}\]
(iv) \[\ce{[Ni(NH3)4Cl2]}\]
Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
Column I (Compound) | Column II (Oxidation state of Co) |
A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
5. + 3 |
Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.
Reason: Unpaired electrons are present in their d-orbitals.
Ethylene diamine tetraacetate (EDTA) ion is ______.
Which of the following species cannot act as a ligand? Give reason.
What is meant by ambidentate ligand?