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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Write the preparation reactions for acid amide from the following. Carboxylic acid - Chemistry

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प्रश्न

Write the preparation reactions for acid amide from the following.

Carboxylic acid

टीपा लिहा

उत्तर

Carboxylic acids react with ammonia to form ammonium carboxylate salt which on further strong heating at high temperature decomposes to give acid amide.

\[\begin{array}{cc}
\phantom{}\ce{O}\phantom{......==.............}\ce{O}\phantom{........................}\ce{O}\phantom{...}\\
\phantom{}||\phantom{.......................}||\phantom{.........................}||\phantom{...}\\
\ce{\underset{\text{Carboxylic acid}}{R - C - OH} + NH3 ⇌ \underset{\text{Ammonium carboxylate}}{R - C - O- - NH^+_4} ->[\Delta][-H2O] \underset{\text{Acid amide}}{R - C - NH2}}
\end{array}\]

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Chemical Properties of Carboxylic Acids
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पाठ 12: Aldehydes, Ketones and Carboxylic acids - Short answer questions (Type-I)

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एससीईआरटी महाराष्ट्र Chemistry [English] 12 Standard HSC
पाठ 12 Aldehydes, Ketones and Carboxylic acids
Short answer questions (Type-I) | Q 6.1

संबंधित प्रश्‍न

Answer in brief.

Formic acid is stronger than acetic acid. Explain.


Correct order of acid strength for

  1. acetic acid
  2. fluoroacetic acid
  3. 4-Nitrobenzoic acid 
  4. 4-Methyl benzoic acid is ______.

Write the structure of the product formed when carboxylic acid is heated with a dehydrating agent like P2O5


What is the action of following on proponal?

Hydroxyl amine


Write reactions for the following conversions.

Propanone to Propane


Write chemical reactions to convert –COOH group of acetic acid into the following.

CH4


Write chemical reactions to convert –COOH group of acetic acid into the following.

CH3COCl


Write reaction for preparation of acetophenone from benzoyl chloride.


Write reactions for the action of the following reagents on p-chlorobenzaldehyde.

Ethane-1,2-diol in presence of dry HCl.


In the reaction,

\[\ce{CH3COOH ->[SOCl2] X ->[Sodium salt of carboxylic acid] Y}\].

The compound Y was found to be a mixed acid anhydride. Thus, the sodium salt of carboxylic acid used CANNOT be ____________.


In the reaction, \[\ce{C6H5COCH3 ->[{[H]}][Zn-Hg/conc. HCl] X}\], X is ______.


Which is the gas evolved when carboxylic acids react with strongly electropositive metals (such as Na, K, Ca, Zn)?


The product of the reaction between dialkyl cadmium and acyl chloride is a/an ____________.


Which of following elements does not form amide when reacted with ammonia?


In the following reaction:

The product X is:


Which of the following carboxylic acids will have the highest acidity?


The elimination of CO2 from a carboxylic acid is known as ____________.


What amount of dinitrogen contains 3.6 × 1018 molecules?


The reducing agent preferred to convert carboxylic acids and esters to primary alcohols is ____________.


Write structure of adipic acid.


Excess of ammonia with sodium hypochloride solution in the presence of glue or gelatine gives ______.


Which of the following can reduce?

\[\ce{RCOOH -> RCH2OH}\]


Draw structures 01 conjugate bases of monochloroacetic acid and dichloroacetic acid. Which one is more stabilized by -I effect?


Identify 'A', 'B' and 'C' in following chain reaction and rewrite the chemical reactions:
\[\ce{CH3CH2OH ->[red 'P'][Br2] A ->[KCN][alc] B ->[LiAlH4][Ether] C}\]

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