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An aromatic carboxylic acid [A], which readily sublimes on heating, produces compound [B] on treatment with PCl5, Compound B, when reduced in the presence of Pd catalyst - Chemistry (Theory)

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Question

An aromatic carboxylic acid [A], which readily sublimes on heating, produces compound [B] on treatment with PCl5, Compound [B], when reduced in the presence of Pd catalyst over BaSO4 poisoned by sulphur in xylene solution, gives compound [C]. When compound [C] is condensed in the presence of alcoholic KCN, it gives compound [D] (Molecular formula of compound [D] is C14H12O2)

Identify the compounds [A], [B], [C] and [D].

Answer in Brief

Solution

[A] = Benzoic acid, [B] = Benzoyl chloride, [C] = Benzaldedhye, [D] = Benzoin

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