Advertisements
Advertisements
Question
Compounds with same molecular formula but differing in their structures are said to be structural isomers. What type of structural isomerism is shown by
CH3 – S – CH2 – CH2 – CH3
And
\[\begin{array}{cc}
\phantom{.....................}\ce{CH3}\\
\phantom{................}/\\
\phantom{}\ce{CH3 - S - CH}\\
\phantom{...............}\backslash\\
\phantom{....................}\ce{CH3}
\end{array}\]
Solution
In the above structures, both have the same functional group (thioether/sulphide), but there is a difference in the arrangement of atoms in the main chain. So they can exhibit chain isomerism.
APPEARS IN
RELATED QUESTIONS
Write IUPAC name of the product obtained by the ozonolysis of the following compound:
2-Ethylbut-1-ene
What effect does branching of an alkane chain has on its boiling point?
Find out the type of isomerism exhibited by the following pair.
Choose the correct option.
Which type of isomerism is possible in CH3 CHCHCH3?
Molecular formula of the functional isomer of methyl formate is ____________.
But-1-ene and But-2-ene are examples of ____________.
What is the relationship between the members of following pairs of structures? Are they structural or geometrical isomers or resonance contributors?
\[\begin{array}{cc}\ce{^+OH}\\||\\
\ce{H - C - OH}\end{array}\]
\[\begin{array}{cc}\ce{OH}\phantom{.}\\|\phantom{...}\\
\ce{H - C^+ - OH}\end{array}\]
In which of the following, functional group isomerism is not possible?
Which of the following pairs are not functional group isomers?
I. | \[\begin{array}{cc} \phantom{.......................}\ce{O}\\ \phantom{.......................}||\\ \ce{CH3 - CH2 - CH2 - CH2 - C - H} \end{array}\] |
II. | \[\begin{array}{cc} \phantom{.................}\ce{O}\\ \phantom{.................}||\\ \ce{CH3 - CH2 - CH2 - C - H} \end{array}\] |
III. | \[\begin{array}{cc} \ce{CH3 - CH2 - C - CH2 - CH3}\\ \phantom{}||\\ \phantom{}\ce{O} \end{array}\] |
IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - C - H}\\ \phantom{...}|\phantom{............}||\phantom{}\\ \phantom{...}\ce{CH3}\phantom{.........}\ce{O}\phantom{} \end{array}\] |
(i) II and III
(ii) II and IV
(iii) I and IV
(iv) I and II
Consider structures I to VII and answer the question:
I. | CH3 – CH2 – CH2 – CH2 – OH |
II. | \[\begin{array}{cc} \ce{CH3 - CH2 - CH - CH3}\\ \phantom{.....}|\\ \phantom{.......}\ce{OH} \end{array}\] |
III. | \[\begin{array}{cc} \phantom{...}\ce{CH3}\\ \phantom{}|\\ \ce{CH3 - C - CH3}\\ \phantom{}|\\ \phantom{..}\ce{OH} \end{array}\] |
IV. | \[\begin{array}{cc} \ce{CH3 - CH - CH2 - OH}\\ |\phantom{........}\\ \ce{CH3}\phantom{......} \end{array}\] |
V. | CH3 – CH2 – O – CH2 – CH3 |
VI. | CH3 – O – CH2 – CH2 – CH3 |
VII. | \[\begin{array}{cc} \ce{CH3 - O - CH - CH3}\\ \phantom{...}|\\ \phantom{......}\ce{CH3} \end{array}\] |
Identify the pairs of compounds that represents position isomerism.
Which of the following does NOT exhibit geometrical isomerism?
The compound which shows metamerism is ______
The correct stereochemical name of
How many structural isomers possible of the molecular formula C3H6O (excluding enol form)?
Which of the following pairs of compounds are positional isomers?
Which of the following reactions will not produce a racemic product?
The number of geometrical isomers from [Co(NH3)3(NO2)3] is ______.