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Karnataka Board PUCPUC Science Class 11

Give a brief description of the principle of the following technique taking an example. Distillation - Chemistry

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Question

Give a brief description of the principle of the following technique taking an example.

Distillation 

Answer in Brief

Solution

Distillation is used to separate volatile liquids from non-volatile impurities or a mixture of those liquids that have a sufficient difference in their boiling points.

Principle: 

It is based on the fact that liquids having different boiling points vapourise at different temperatures. The vapours are then cooled and the liquids so formed are collected separately.

For example, a mixture of chloroform (b.p = 334 K) and aniline (b.p = 457 K) can be separated by the method of distillation. The mixture is taken in a round bottom flask fitted with a condenser. It is then heated. Chloroform, being more volatile, vaporizes first and passes into the condenser. In the condenser, the vapours condense and chloroform trickles down. In the round bottom flask, aniline is left behind.

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Chapter 12: Organic Chemistry - Some Basic Principles and Techniques - EXERCISES [Page 371]

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NCERT Chemistry - Part 1 and 2 [English] Class 11
Chapter 12 Organic Chemistry - Some Basic Principles and Techniques
EXERCISES | Q 12.18 - (b) | Page 371

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