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Question
How are the following conversions carried out?
Benzoic acid into metanitrobenzoic acid.
Solution
Conversion of benzoic acid into meta-nitrobenzoic acid
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RELATED QUESTIONS
State the superiority of crystal field theory over valence bond theory.
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(i) \[\ce{[MnCl6]^{3-}}\]
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(i) \[\ce{[Co(H2O)6]^{2+}}\] is transformed into \[\ce{[CoCl6]}^{4-}\]
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(iv) tetrahedral complexes have larger crystal field splitting than octahedral complex.
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\[\ce{[CoF6]^{3-}, [Fe(CN)6]^{4-} and [Cu(NH3)6]^{2+}}\].
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Using crystal field theory, draw energy level diagram, write electronic configuration of the central metal atom/ion and determine the magnetic moment value in the following:
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The CFSE for octahedral [CoCl6]−4 is 18,000 cm−1. What will be the CFSE for tetrahedral [CoCl3]−2?
[Ni(H2O)6]2+ (aq) is green in colour whereas [Ni(H2O)4 (en)]2+ (aq)is blue in colour, give reason in support of your answer.
Considering crystal field theory, strong-field ligands such as CN–:
Crystal field stabilising energy for high spind4 octahedral complex is:-
Using crystal field theory, write the electronic configuration of d5 ion, if Δ0 > P.
What is the difference between a weak field ligand and a strong field ligand?
The correct order of intensity of colors of the compounds is ______.
For octahedral Mn(II) and tetrahedral Ni(II) complexes, consider the following statements:
(i) Both the complexes can be high spin.
(ii) Ni(II) complex can very rarely below spin.
(iii) With strong field Ligands, Mn(II) complexes can be low spin.
(iv) Aqueous solution of Mn (II) ions is yellow in colour.
The correct statements are:
The complex that has highest crystal field splitting energy (Δ) is ______.
On the basis of crystal field theory, write the electronic configuration for d4 with a strong field ligand for which Δ0 > P.
Explain the difference between a weak field ligand and a strong field ligand.
