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Identify the correct statements with reference to the given reaction. PX4+3OHX−+3HX2O⟶PHX3+3HX2POX2− (i) Phosphorus is undergoing reduction only. (ii) Phosphorus is undergoing oxidati - Chemistry

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Question

Identify the correct statements with reference to the given reaction.

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

(i) Phosphorus is undergoing reduction only.

(ii) Phosphorus is undergoing oxidation only.

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.

Short Note

Solution

(iii) Phosphorus is undergoing oxidation as well as reduction.

(iv) Hydrogen is undergoing neither oxidation nor reduction.

Explanation:

The given reaction is as below-

\[\ce{P4 + 3OH- + 3H2O -> PH3 + 3H2PO^{-}2}\]

The above reaction is a kind of disproportionate reaction in which phosphorous is being reduced as well as oxidized whereas hydrogen remains same in +1 oxidation state. 

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Oxidation Number - Types of Redox Reactions
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Chapter 8: Redox Reactions - Multiple Choice Questions (Type - I) [Page 107]

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NCERT Exemplar Chemistry [English] Class 11
Chapter 8 Redox Reactions
Multiple Choice Questions (Type - I) | Q 15 | Page 107

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