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Questions
Show how the following compound can be converted to benzoic acid.
Phenylethene (Styrene)
How are the following conversions carried out?
Phenylethene into Benzoic acid
Solution 1
Solution 2
Conversion of phenylethene into benzoic acid:
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\[\begin{array}{cc}
\phantom{....................}\ce{O}\phantom{.....................................}\ce{O}\phantom{.}\\
\phantom{....................}||\phantom{......................................}||\phantom{.}\\
\phantom{}\ce{CH3 - CH = CH - CH2 - C - CH3 -> CH3 - CH = CH - CH2 - C - OH}\phantom{.}
\end{array}\]
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Column I (Reactions) |
Column II (Reagents) |
(i) Benzophenone Diphenylmethane | (a) \[\ce{LiAlH4}\] |
(ii) Benzaldehyde 1-Phenylethanol | (b) \[\ce{DIBAL-H}\] |
(iii) Cyclohexanone Cyclohexanol | (c) \[\ce{Zn(Hg)/Conc. HCl}\] |
(iv) Phenyl benzoate Benzaldehyde | (d) \[\ce{CH3MgBr}\] |
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List - I | List - II | ||
(a) | ![]() |
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(b) |
\[\begin{array}{cc}
\ce{O}\phantom{.................}\\ ||\phantom{.................}\\ \ce{R - C - CH3 + NaOX ->} \end{array}\] |
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(d) | \[\ce{R - CH2COOH ->[(i) X2/Red P][(ii) H2O]}\] | (iv) | Esterification |
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