Advertisements
Advertisements
Question
Using valence bond theory, explain the following in relation to the complexes given below:
\[\ce{[Co(NH3)6]^{3+}}\]
(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.
Solution
\[\ce{[Co(NH3)6]^{3+}}\]:
(i) Hybridisation – d2sp3
(ii) Inner orbital complex
(iii) Diamagnetic
(iv) Magnetic moment = `0
APPEARS IN
RELATED QUESTIONS
[Cr(NH3)6]3+ is paramagnetic while [Ni(CN)4]2− is diamagnetic. Explain why?
Discuss the nature of bonding in the following coordination entity on the basis of valence bond theory:
[Co(C2O4)3]3−
[NiCl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why? (Atomic no. Ni = 28)
Using valence bond theory, explain the following in relation to the complexes given below:
\[\ce{[Cr(H2O)6]^{3+}}\]
(i) Type of hybridisation.
(ii) Inner or outer orbital complex.
(iii) Magnetic behaviour.
(iv) Spin only magnetic moment value.
The type of hybridization involved in Octahedral complexes is ______.
Which of the statement given below is incorrect about H2O2?
Which of the following has square planar structures?
In Fe(CO)5, the Fe – C bond possesses
Using Valence bond theory, explain the following in relation to the paramagnetic complex [Mn(CN)6]3-
- type of hybridization
- magnetic moment value
- type of complex – inner, outer orbital complex
Using valence bond theory, predict the hybridization and magnetic character of the following:
[CoF6]3– [Atomic number of Co = 27]