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Why are elemental dopants for Silicon or Germanium usually chosen from group XIII or group XV? - Physics

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Question

Why are elemental dopants for Silicon or Germanium usually chosen from group XIII or group XV?

Short Note

Solution

The size of dopant atoms should be such as not to distort the pure semiconductor lattice structure and yet easily contribute a charge carrier on forming covalent bonds with Si or Ge.

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Chapter 14: Semiconductor Electronics - Exercises [Page 91]

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NCERT Exemplar Physics [English] Class 12
Chapter 14 Semiconductor Electronics
Exercises | Q 14.17 | Page 91
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