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Write chemical test to distinguish between the following compounds: Phenol and Benzoic acid - Chemistry

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Write chemical test to distinguish between the following compounds:

Phenol and Benzoic acid

Give chemical test to distinguish between the following pair of compound:

Phenol and Benzoic acid

Distinguish Between

Solution 1

Phenol and Benzoic Acid can be distinguished by the iron chloride FeCl3 test. As phenol gives violet colouration with neutral FeCl3, solution while benzoic acid gives buff-coloured precipitate of ferric benzoate.

6CA6HA5OH+FeClA3[Fe(OCA6HA5)A6]A3Violet complex+3HA++3HCl

3CA6HA5COOHBenzoic acid+FeClA3(CA6HA5COO)A3FeBuff coloured ppt+3HCl

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Solution 2

Reagent Phenol Benzoic acid
Neutral ferric chloride When phenol is treated with ferric chloride, there is a change in colour; the product formed is either green, blue, purple, or red. No change in the colour of benzoic acid.
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2021-2022 (April) Term 2 - Delhi Set 2

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