Advertisements
Advertisements
प्रश्न
For the reaction 2A + B → C, rate of disappearance of A 0.076 mol s –1.
- What is the rate of formation of C?
- What is the rate of consumption of B?
- What is the rate of the overall reaction?
उत्तर
Given: Rate of disappearance of A = `- ("d"["A"])/"dt"` = 0.076 mol s-1
To find:
- Rate of formation of C
- Rate of consumption of B
- Rate of the overall reaction
Calculation:
Rate of reaction = `- 1/2 ("d"["A"])/"dt" = - ("d"["B"])/"dt" = ("d"["C"])/"dt"`
Rate of formation of C = `("d"["C"])/"dt" = - 1/2 ("d"["A"])/"dt"`
`= 1/2 xx 0.076` mol s-1
= 0.038 mol s-1
Rate of consumption of B = `- ("d"["B"])/"dt" = - 1/2 ("d"["A"])/"dt"`
`= 1/2 xx 0.076` mol s-1
= 0.038 mol s-1
Rate of reaction = `("d"["C"])/"dt"` = 0.038 mol s-1
- Rate of formation of C= 0.038 mol s-1
- Rate of consumption of B = 0.038 mol s-1
- Rate of the overall reaction = 0.038 mol s-1
संबंधित प्रश्न
The time required for 90% completion of a certain first-order reaction is t. The time required for 99.9% completion will be _________.
Choose the most correct option.
The reaction, \[\ce{3ClO- -> ClO^-3 + 2Cl-}\] occurs in two steps,
(i) \[\ce{2ClO- -> ClO^-2}\]
(ii) \[\ce{ClO^-2 + ClO- -> ClO^-_3 + Cl-}\]
The reaction intermediate is _______.
Choose the most correct option.
Rate law for the reaction, \[\ce{2NO + Cl2 -> 2NOCl}\] is rate = k[NO2]2[Cl2]. Thus of k would increase with _____________.
Answer the following in brief.
For the reaction 2A + B → products, find the rate law from the following data.
[A]/M | [B]/M | rate/M s-1 |
0.3 | 0.05 | 0.15 |
0.6 | 0.05 | 0.30 |
0.6 | 0.2 | 1.20 |
Answer the following in one or two sentences.
For the reaction,
\[\ce{CH3Br_{(aq)} + OH^-_{ (aq)} -> CH3OH^-_{ (aq)} + Br^-_{ (aq)}}\], rate law is rate = k`["CH"_3"Br"]["OH"^-]`
What is the change in rate if concentrations of both reactants are doubled?
A First order reaction is 50% complete in 69.3 minutes. Time required for 90% completion for the same reaction is _______.
The rate law relates to the rate of a chemical reaction in terms of _______.
Order of reaction for which unit of rate constant is mol dm–3 s–1 is _______.
A reaction occurs in the following steps:
Step 1: \[\ce{NO_{2(g)} + F_2 -> NO2F_{(g)} + F_{(g)}}\] (slow)
Step 2: \[\ce{F_{(g)} + NO_{2(g)} -> NO_2F}\] (Fast)
- Write the equation of overall reaction.
- Write the rate law.
- Identify reaction intermediate.
In a hypothetical reaction,
\[\ce{2A + B -> Products}\]. Rate = k [A]2 [B]
Molar concentration of 'B' is kept constant and molar concentration of 'A' is tripled, then the rate of reaction will ____________.
The rate constant of a first order reaction whose half-life is 480 seconds, is ____________.
For the reaction, \[\ce{N2(g) + 3H2(g) -> 2NH3(g); \Delta H}\] is equal to ______.
The rate law for a reaction between the substances A and B is given by, rate = k[A]n [B]m. On halving the concentration of A and doubling the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as ____________.
For a chemical reaction rate law is, rate = k[A]2[B]. If [A] is doubled at constant [B], the rate of reaction ______.
The order of the reaction occurring by following mechanism should be:
(i) \[\ce{A2 + B2 -> AB2 + A (slow)}\]
(ii) \[\ce{A + B2 -> AB2 (fast)}\]
Consider the reaction \[\ce{2A + 2B -> C + 2D}\], if concentration of A is doubled at constant [B], rate increases by a factor 4. If concentration B is doubled at constant [A] the rate is doubled. Rate law of the reaction is ____________.
In the reaction \[\ce{A + B2 -> AB + B}\], the rate of reaction is directly proportional to the concentration of A and independent on the concentration of B2. What is the rate law expression?
The reaction \[\ce{A + B -> P}\], is second order in A and first order in B. What is the rate law for the reaction?
In the reaction, \[\ce{N2 + 3H2 -> 2NH3}\], the rate of disappearance of H2 is 0.02 Mis. The rate of appearance of NH3 is ______.
What is the order of reaction for decomposition of gaseous acetaldehyde?
What is the molecularity and order of the following reaction if rate law is, rate = k[O3][O] respectively.
\[\ce{O_{3(g)} + O_{(g)} -> 2O_{2(g)}}\]
In the reaction \[\ce{2SO_{2_{(g)}} O_{2_{(g)}} -> 2SO_{3_{(g)}}}\], the rate of disappearance of SO2 is 1.28 × 10-5 M/s. What is the rate of appearance of SO3?
Which of the following unit is used to express the rate of a reaction?
The correct order of raaii of F, F-, O and O2- is ______.
Write the rate law for the following reaction:
A reaction that is zero order in A and second order in B.
For the reaction A + B → P.
If [B] is doubled at constant [A], the rate of reaction doubled. If [A] is triple and [B] is doubled, the rate of reaction increases by a factor of 6. Calculate the rate law equation.