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The value of rate constant of a pseudo first order reaction ______. - Chemistry

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प्रश्न

The value of rate constant of a pseudo first order reaction ______.

विकल्प

  • depends on the concentration of reactants present in small amount.

  • depends on the concentration of reactants present in excess.

  • is independent of the concentration of reactants.

  • depends only on temperature.

MCQ
रिक्त स्थान भरें

उत्तर

The value of rate constant of a pseudo first order reaction depends on the concentration of reactants present in excess.

Explanation:

Let's start with what a pseudo-first-order response is.

Although the pseudo-first-order reaction looks to be an order, it belong to another order. it's a second-order reaction because it involves two reactants.

Let's have a look at a reaction.

\[\ce{CH3Br + OH -> CH3OH + Br}\]

So, the rate law for the reaction is 

Rate = \[\ce{k[OH][CH3Br]}\]

Rate = \[\ce{k[OH][CH3Br] = k(constant) [CH3Br] = K' [CH3Br]}\]

Only the concentration of \[\ce{CH3Br}\] will change during the reaction and the rate will be determined by the reaction's modifications.

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अध्याय 4: Chemical Kinetics - Exercises [पृष्ठ ५२]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 4 Chemical Kinetics
Exercises | Q I. 19. | पृष्ठ ५२

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